• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

超流氦的高度带电液滴。

Highly Charged Droplets of Superfluid Helium.

机构信息

Institut für Ionenphysik und Angewandte Physik, Universität Innsbruck, Technikerstr. 25, A-6020 Innsbruck, Austria.

Departamento de Física-ICE, Universidade Federal de Juiz de Fora, Campus Universitário, 36036-900, Juiz de Fora, MG, Brazil.

出版信息

Phys Rev Lett. 2019 Oct 18;123(16):165301. doi: 10.1103/PhysRevLett.123.165301.

DOI:10.1103/PhysRevLett.123.165301
PMID:31702350
Abstract

We report on the production and study of stable, highly charged droplets of superfluid helium. Using a novel experimental setup we produce neutral beams of liquid helium nanodroplets containing millions of atoms or more that can be ionized by electron impact, mass-per-charge selected, and ionized a second time before being analyzed. Droplets containing up to 55 net positive charges are identified and the appearance sizes of multiply charge droplets are determined as a function of the charge state. We show that the droplets are stable on the millisecond timescale of the experiment and decay through the loss of small charged clusters, not through symmetric Coulomb explosions.

摘要

我们报告了超流氦稳定、高电荷液滴的产生和研究。使用一种新颖的实验装置,我们产生了含有数百万个原子或更多原子的中性液氦纳米液滴束,这些液滴可以通过电子碰撞电离,按质荷比选择,并在被分析之前再次被电离。我们识别出含有多达 55 个净正电荷的液滴,并确定了多电荷液滴的表观尺寸作为电荷状态的函数。我们表明,液滴在实验的毫秒时间尺度上是稳定的,并通过小的带电团簇的损失而衰减,而不是通过对称的库仑爆炸。

相似文献

1
Highly Charged Droplets of Superfluid Helium.超流氦的高度带电液滴。
Phys Rev Lett. 2019 Oct 18;123(16):165301. doi: 10.1103/PhysRevLett.123.165301.
2
Multiply Charged Helium Droplet Anions.多电荷氦滴阴离子
Chemistry. 2021 May 3;27(25):7283-7287. doi: 10.1002/chem.202005004. Epub 2021 Mar 12.
3
Electron Diffraction of Ionic Argon Nanoclusters Embedded in Superfluid Helium Droplets.嵌入超流氦滴中的离子氩纳米团簇的电子衍射
J Phys Chem Lett. 2021 Oct 7;12(39):9644-9650. doi: 10.1021/acs.jpclett.1c02712. Epub 2021 Sep 29.
4
Electron diffraction as a structure tool for charged and neutral nanoclusters formed in superfluid helium droplets.电子衍射作为一种用于研究超流氦滴中形成的带电和中性纳米团簇结构的工具。
Phys Chem Chem Phys. 2022 Mar 16;24(11):6349-6362. doi: 10.1039/d2cp00048b.
5
Revisiting Thomson's model with multiply charged superfluid helium nanodroplets.
J Chem Phys. 2024 Dec 14;161(22). doi: 10.1063/5.0244260.
6
Anthracene-Argon Clusters Generated in Superfluid Helium Nanodroplets: New Aspects on Cluster Formation and Microsolvation.超流氦纳米液滴中生成的蒽-氩团簇:簇形成和微溶剂化的新方面。
J Phys Chem A. 2020 Jan 16;124(2):311-321. doi: 10.1021/acs.jpca.9b04138. Epub 2019 Jul 1.
7
Facile time-of-flight methods for characterizing pulsed superfluid helium droplet beams.用于表征脉冲超流氦滴束的简便飞行时间方法。
Rev Sci Instrum. 2015 Aug;86(8):084102. doi: 10.1063/1.4928107.
8
Helium superfluidity. Shapes and vorticities of superfluid helium nanodroplets.氦超流性。超流氦纳米液滴的形状和涡度。
Science. 2014 Aug 22;345(6199):906-9. doi: 10.1126/science.1252395.
9
Superfluid helium droplet-mediated surface-deposition of neutral and charged silver atomic species.超流氦液滴介导的中性和带电银原子物种的表面沉积。
Phys Chem Chem Phys. 2023 Jun 28;25(25):16699-16706. doi: 10.1039/d3cp01303k.
10
Efficient Formation of Size-Selected Clusters upon Pickup of Dopants into Multiply Charged Helium Droplets.掺杂剂进入多电荷氦液滴中后,通过提取形成尺寸选择的团簇。
Int J Mol Sci. 2022 Mar 25;23(7):3613. doi: 10.3390/ijms23073613.

引用本文的文献

1
Spectroscopic investigation of size-dependent CO binding on cationic copper clusters: analysis of the CO asymmetric stretch.阳离子铜簇上尺寸依赖性 CO 吸附的光谱研究:CO 不对称伸缩振动分析
Phys Chem Chem Phys. 2024 Jul 31;26(30):20355-20364. doi: 10.1039/d4cp01797h.
2
Size limits and fission channels of doubly charged noble gas clusters.双电荷惰性气体团簇的尺寸限制和裂变通道
Phys Chem Chem Phys. 2024 May 8;26(18):13923-13936. doi: 10.1039/d4cp00658e.
3
Doubly charged dimers and trimers of heavy noble gases.重稀有气体的双电荷二聚体和三聚体。
Phys Chem Chem Phys. 2024 Apr 17;26(15):11482-11490. doi: 10.1039/d4cp00465e.
4
Gas-Phase Electronic Structure of Phthalocyanine Ions: A Study of Symmetry and Solvation Effects.酞菁离子的气相电子结构:对称性与溶剂化效应研究
Adv Sci (Weinh). 2024 Mar;11(12):e2307816. doi: 10.1002/advs.202307816. Epub 2024 Jan 15.
5
Solvation of cationic copper clusters in molecular hydrogen.阳离子铜簇在分子氢中的溶剂化作用。
Phys Chem Chem Phys. 2023 Sep 27;25(37):25251-25263. doi: 10.1039/d3cp03452f.
6
Observation of Multiple Ordered Solvation Shells in Doped Helium Droplets: The Case of HeCa.观察掺杂氦液滴中的多个有序溶剂化壳:以 HeCa 为例。
J Phys Chem Lett. 2023 Apr 6;14(13):3126-3131. doi: 10.1021/acs.jpclett.3c00224. Epub 2023 Mar 23.
7
Structure and formation of copper cluster ions in multiply charged He nanodroplets.氦纳米液滴中多电荷铜团簇离子的结构和形成。
Phys Chem Chem Phys. 2023 Mar 22;25(12):8463-8471. doi: 10.1039/d2cp04569a.
8
Non-ergodic fragmentation upon collision-induced activation of cysteine-water cluster cations.非遍历碎裂:由半胱氨酸-水团簇离子碰撞引发的激活。
Phys Chem Chem Phys. 2023 Feb 15;25(7):5361-5371. doi: 10.1039/d2cp04172c.
9
Helium nanodroplets as an efficient tool to investigate hydrogen attachment to alkali cations.氦纳米液滴作为一种有效工具,用于研究氢原子与碱金属阳离子的结合。
Phys Chem Chem Phys. 2022 Dec 21;25(1):462-470. doi: 10.1039/d2cp03841b.
10
Electronic spectroscopy of cationic adamantane clusters and dehydrogenated adamantane in helium droplets.氦滴中阳离子金刚烷簇和脱氢金刚烷的电子光谱。
Phys Chem Chem Phys. 2022 Oct 5;24(38):23142-23151. doi: 10.1039/d2cp03523e.