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基于 MXene/银纳米复合材料的高灵敏度和高拉伸应变传感器的制备及其在可穿戴设备中的应用。

Preparation of a Highly Sensitive and Stretchable Strain Sensor of MXene/Silver Nanocomposite-Based Yarn and Wearable Applications.

机构信息

Key Laboratory of Textile Science & Technology, Ministry of Education, College of Textiles , Donghua University , Shanghai 201620 , People's Republic of China.

出版信息

ACS Appl Mater Interfaces. 2019 Dec 11;11(49):45930-45938. doi: 10.1021/acsami.9b19242. Epub 2019 Nov 22.

Abstract

As a wearable device, highly sensitive and stretchable strain sensors should be integrated to monitor various daily actions, which include large- and small-scale strains, such as jumping, running, heartbeat, and pulse. At present, the method of preparing strain sensors is mainly to impregnate or load materials like graphene, carbon nanotube, and their union products on elastic substrates to obtain highly sensitive characteristics. Both well-known carbon-based and other single-dimensional nanomaterials do not have high flexibility and conductivity, which limits the improvement of sensitivity. However, a novel material MXene TiCT has a two-dimensional (2D) sheet structure, which allows for higher electron and ion transmission rates. In addition, it is easier to be combined with other nanomaterials as a nanosubstrate, greatly improving malleability. Hence, we creatively prepared zero-dimensional (0D)-one-dimensional (1D)-2D multi-dimensional nanomaterials, which designed 0D silver nanoparticles (AgNPs) loaded on 2D MXene nanosheets and compounded with 1D silver nanowires (AgNWs). The method improves the elasticity and conductivity of traditional single-dimensional materials, wherein AgNPs built a bridge between AgNWs and MXene, which ensures continuity and a high gauge factor even at a large strain (200%) of yarn. The composite yarn strain sensor has a remarkably high strain and sensitivity, effectively monitoring the large and small deformations of various parts of the human body, whose fabric can be an electrothermal device. It has vital inspiration for the development of intelligent textiles, which would be used in medical devices, artificial skin, and other wearable fields.

摘要

作为一种可穿戴设备,高灵敏度和可拉伸的应变传感器应集成在一起,以监测各种日常动作,包括大、小应变,如跳跃、跑步、心跳和脉搏。目前,制备应变传感器的方法主要是将石墨烯、碳纳米管及其联合产品等材料浸渍或负载在弹性基底上,以获得高灵敏度的特性。众所周知的碳基和其他一维纳米材料都没有高的柔韧性和导电性,这限制了灵敏度的提高。然而,一种新型材料 MXene TiCT 具有二维(2D)片层结构,允许更高的电子和离子传输率。此外,它更容易与其他纳米材料结合作为纳米基底,大大提高了延展性。因此,我们创造性地制备了零维(0D)-一维(1D)-二维(2D)多维纳米材料,设计了 0D 银纳米粒子(AgNPs)负载在 2D MXene 纳米片上,并与 1D 银纳米线(AgNWs)复合。该方法提高了传统一维材料的弹性和导电性,其中 AgNPs 在 AgNWs 和 MXene 之间架起了桥梁,即使在纱线大应变(200%)下也能保证连续性和高的应变系数。该复合纱应变传感器具有显著的高应变和灵敏度,能有效监测人体各部位的大、小变形,其织物可以作为电热装置。这对智能纺织品的发展具有重要的启示,它将用于医疗器械、人造皮肤和其他可穿戴领域。

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