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用于多功能应用的基于MXene的纳米材料。

MXene-Based Nanomaterials for Multifunctional Applications.

作者信息

Perera A A P R, Madhushani K A U, Punchihewa Buwanila T, Kumar Anuj, Gupta Ram K

机构信息

Department of Chemistry, Pittsburg State University, Pittsburg, KS 66762, USA.

National Institute for Materials Advancement, Pittsburg State University, Pittsburg, KS 66762, USA.

出版信息

Materials (Basel). 2023 Jan 29;16(3):1138. doi: 10.3390/ma16031138.

Abstract

MXene is becoming a "rising star" material due to its versatility for a wide portfolio of applications, including electrochemical energy storage devices, electrocatalysis, sensors, biomedical applications, membranes, flexible and wearable devices, etc. As these applications promote increased interest in MXene research, summarizing the latest findings on this family of materials will help inform the scientific community. In this review, we first discuss the rapid evolutionary change in MXenes from the first reported MXT structure to the last reported MXT structure. The use of systematically modified synthesis routes, such as foreign atom intercalation, tuning precursor chemistry, etc., will be further discussed in the next section. Then, we review the applications of MXenes and their composites/hybrids for rapidly growing applications such as batteries, supercapacitors, electrocatalysts, sensors, biomedical, electromagnetic interference shielding, membranes, and flexible and wearable devices. More importantly, we notice that its excellent metallic conductivity with its hydrophilic nature distinguishes MXene from other materials, and its properties and applications can be further modified by surface functionalization. MXene composites/hybrids outperform pristine MXenes in many applications. In addition, a summary of the latest findings using MXene-based materials to overcome application-specific drawbacks is provided in the last few sections. We hope that the information provided in this review will help integrate lab-scale findings into commercially viable products.

摘要

由于MXene在包括电化学储能装置、电催化、传感器、生物医学应用、膜、柔性和可穿戴设备等广泛应用组合中的多功能性,它正成为一种“后起之秀”材料。随着这些应用激发了对MXene研究的更多兴趣,总结关于这类材料的最新发现将有助于为科学界提供信息。在本综述中,我们首先讨论了MXene从首次报道的MXT结构到最后报道的MXT结构的快速演变。下一节将进一步讨论系统修饰的合成路线的使用,如外来原子插层、调整前驱体化学性质等。然后,我们综述了MXene及其复合材料/杂化物在电池、超级电容器、电催化剂、传感器、生物医学、电磁干扰屏蔽、膜以及柔性和可穿戴设备等快速发展的应用中的应用。更重要的是,我们注意到其优异的金属导电性及其亲水性使MXene有别于其他材料,并且其性质和应用可以通过表面功能化进一步修饰。MXene复合材料/杂化物在许多应用中优于原始MXene。此外,最后几节提供了使用基于MXene的材料克服特定应用缺点的最新发现总结。我们希望本综述中提供的信息将有助于将实验室规模的发现整合到商业上可行的产品中。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f416/9920486/53a1b16191c2/materials-16-01138-g001.jpg

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