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高效液相色谱法测定浸泡过甲萘威的黄瓜和辣椒中化学溶液去除甲萘威残留的效果。

The effectiveness of chemical solutions on the removal of carbaryl residues from cucumber and chili presoaked in carbaryl using the HPLC technique.

机构信息

Biochemistry Unit, Medical Science Department, Faculty of Science, Rangsit University, Pathumthani 12000, Thailand.

Biochemistry Unit, Medical Science Department, Faculty of Science, Rangsit University, Pathumthani 12000, Thailand.

出版信息

Food Chem. 2020 Mar 30;309:125659. doi: 10.1016/j.foodchem.2019.125659. Epub 2019 Nov 6.

Abstract

This research aimed to compare the efficiency of five washing solutions (0.9% NaCl, 0.1% NaHCO, DI water, 0.001% KMnO and 0.1% acetic acid) for removing carbaryl residues from cucumber and chili. The vegetables were soaked in 10 mg/L of carbaryl solution for 30 min and then washed for 30 min in one of the five washing solutions and the results compared. Each experiment was performed in triplicate and the amounts of carbaryl residues remaining were determined using high-performance liquid chromatography (HPLC). The results showed that 0.001% KMnO was the most effective at removing carbaryl from both vegetables. Washing with 0.001% KMnO reduced carbaryl residues to 64% and 28%, respectively, of the original concentrations. Washing with DI water was the least effective method of removing carbaryl residues. Hopefully, the results will encourage further research, into reducing carbaryl contamination by washing with chemical solutions, which will enable producers to reduce pesticide residues.

摘要

本研究旨在比较五种洗涤液(0.9% NaCl、0.1% NaHCO₃、去离子水、0.001% KMnO₄和 0.1% 乙酸)去除黄瓜和辣椒中残杀威的效率。将蔬菜浸泡在 10mg/L 的残杀威溶液中 30 分钟,然后在这五种洗涤液中的一种中洗涤 30 分钟,并比较结果。每个实验重复进行三次,使用高效液相色谱法(HPLC)测定残杀威残留量。结果表明,0.001% KMnO₄对两种蔬菜去除残杀威最有效。用 0.001% KMnO₄洗涤后,残杀威残留量分别降低到原始浓度的 64%和 28%。用去离子水洗涤是去除残杀威残留最无效的方法。希望这些结果将鼓励进一步研究,通过用化学溶液洗涤来减少残杀威的污染,从而使生产者能够减少农药残留。

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