Multifunctional Catalytic Surface Design for Concerted Acceleration of One-Pot Hydrosilylation-CO Cycloaddition.

Silica-supported Rh-ammonium iodide catalyst showed high performance for hydrosilylation-CO cycloaddition reaction sequences. The catalyst was prepared by surface grafting of Rh and the silane-coupling reaction of the ammonium iodide moiety. The acceleration of each catalytic reaction was realized due to the concerted catalysis between Rh species, immobilized organic functions, and surface Si-OH groups. As a result, good to excellent yields of silyl carbonates were obtained from epoxyolefins, hydrosilanes, and CO under mild reaction conditions.