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简单环保的纳米银导电墨水的制备工艺及其在频率选择表面中的应用。

Simple and green fabrication process of nano silver conductive ink and the application in frequency selective surface.

机构信息

College of Materials Science and Engineering, Changsha University of Science and Technology, Changsha, People's Republic of China.

出版信息

Nanotechnology. 2020 Mar 6;31(10):105705. doi: 10.1088/1361-6528/ab5a0f. Epub 2019 Nov 21.

Abstract

A simple and green method for fabrication of nano silver conductive ink was developed for use in frequency selective surface (FSS). The hydrogen peroxide and ethyl cellulose were used as reducing agents and dispersants to synthesize silver nanoparticles (Ag NPs), and the ethyl cellulose was be used as binders of nano silver conductive ink eventually. The reaction byproducts of hydrogen peroxide are water and oxygen, the synthesized Ag NPs were be cleaned using purified water and alcohol without centrifugation and drying process. The conductive ink with 30 wt% silver content was formulated with the Ag NPs capped with ethyl cellulose, solvent and additive, the residual water and alcohol were be evaporated using vacuum distillation process. The prepared Ag NPs were characterized by SEM, XRD, TGA and FT-IR. The viscosity and surface tension of Ag NPs ink were tested, and the conductive ink was inkjet printed on Polyimide (PI) film to fabricate the FSS. The results showed the printed FSS had reflection resonances at 16.5 GHz and nulls deeper than the required -20 dB level, with depths of -32 dB.

摘要

开发了一种用于频率选择表面(FSS)的纳米银导电油墨的简单绿色制造方法。用过氧化氢和乙基纤维素作为还原剂和分散剂来合成银纳米粒子(Ag NPs),最终乙基纤维素用作纳米银导电油墨的粘合剂。过氧化氢的反应副产物是水和氧气,合成的 Ag NPs 无需离心和干燥过程,使用纯净水和酒精进行清洗。含有 30wt%银含量的导电油墨由乙基纤维素封端的 Ag NPs、溶剂和添加剂制成,通过真空蒸馏除去残留的水和酒精。通过 SEM、XRD、TGA 和 FT-IR 对 Ag NPs 进行了表征。测试了 Ag NPs 油墨的粘度和表面张力,并将导电油墨喷墨打印在聚酰亚胺(PI)薄膜上以制造 FSS。结果表明,打印的 FSS 在 16.5GHz 处具有反射共振,并且低于所需的-20dB 水平的陷波深度达到-32dB。

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