硒酰胺调节 1,3,5-取代苯的氢键超分子聚合物中的偶极-偶极相互作用。
Selenoamides modulate dipole-dipole interactions in hydrogen bonded supramolecular polymers of 1,3,5-substituted benzenes.
机构信息
Institute for Complex Molecular Systems, Eindhoven University of Technology, P. O Box 513, 5600 MB Eindhoven, The Netherlands.
出版信息
Chem Commun (Camb). 2019 Dec 25;55(99):14906-14909. doi: 10.1039/c9cc08423a. Epub 2019 Nov 26.
PMID:31769447
Abstract
We report the synthesis and self-assembly behavior of a chiral C-symmetrical benzene-tricarboselenoamide. The introduction of the selenoamide moiety enhances the dipolar character of the supramolecular interaction and confers a remarkable thermal stability to the supramolecular polymers obtained.
摘要
我们报告了一种手性 C 对称苯三碳硒酰胺的合成和自组装行为。硒酰胺部分的引入增强了超分子相互作用的偶极性质，并赋予了所得到的超分子聚合物显著的热稳定性。
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