镍催化卤代烷与卤代芳烃的电化学还原接力交叉偶联反应
Nickel-Catalyzed Electrochemical Reductive Relay Cross-Coupling of Alkyl Halides to Aryl Halides.
作者信息
Jiao Ke-Jin, Liu Dong, Ma Hong-Xing, Qiu Hui, Fang Ping, Mei Tian-Sheng
机构信息
State Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Road, Shanghai, 200032, China.
School of Chemistry and Chemical Engineering, Yancheng Institute of Technology, Yancheng, 224051, China.
出版信息
Angew Chem Int Ed Engl. 2020 Apr 16;59(16):6520-6524. doi: 10.1002/anie.201912753. Epub 2019 Dec 30.
A highly regioselective Ni-catalyzed electrochemical reductive relay cross-coupling between an aryl halide and an alkyl halide has been developed in an undivided cell. Various functional groups are tolerated under these mild reaction conditions, which provides an alternative approach for the synthesis of 1,1-diarylalkanes.
在无隔膜电解池中，已开发出一种高度区域选择性的镍催化电化学还原接力交叉偶联反应，用于芳基卤化物和烷基卤化物之间的反应。在这些温和的反应条件下，各种官能团都能耐受，这为合成1,1-二芳基烷烃提供了一种替代方法。
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