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水合硼酸盐的红外光谱

Infrared Spectra of the Hydrated Borates.

作者信息

Weir C E

机构信息

Institute for Materials Research, National Bureau of Standards, Washington, D.C.

出版信息

J Res Natl Bur Stand A Phys Chem. 1966 Mar-Apr;70A(2):153-164. doi: 10.6028/jres.070A.012.

Abstract

Infrared absorption spectra of 42 different hydrated borates were obtained in the 2000-300 cm range. A few spectra were obtained between 4000 and 2000 cm. Most spectra are complex and cannot be interpreted satisfactorily except in the case of the simplest anions. Many correlations between spectra are possible, however, and possible anion types have been deduced. Differentiation between triangular and tetrahedral boron is possible on the basis of the spectra but IS less certain than in the case of the anhydrous borates.

摘要

在2000-300厘米范围内获得了42种不同水合硼酸盐的红外吸收光谱。在4000至2000厘米之间获得了少数光谱。大多数光谱都很复杂,除了最简单的阴离子情况外,无法得到令人满意的解释。然而,光谱之间存在许多可能的关联,并且已经推断出可能的阴离子类型。根据光谱可以区分三角硼和四面体硼,但不如无水硼酸盐的情况那么确定。

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本文引用的文献

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Infrared Studies of Aragonite, Calcite, and Vaterite Type Structures in the Borates, Carbonates, and Nitrates.
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Pentaborate Polyanion in the Crystal Structure of Ulexite, NaCaB5O6(OH)6{middle dot}5H2O.
Science. 1964 Sep 18;145(3638):1295-6. doi: 10.1126/science.145.3638.1295.

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