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利用碳氮同位素分析新旧梯级水库总有机碳源差异

[Analysis of Total Organic Carbon Source Differences Between New and Old Cascade Reservoirs using Carbon and Nitrogen Isotopes].

作者信息

Wang Cong-Feng, Hu Zi-Long, Yang Zheng-Jian, Dan Yong, Zhao Ping, Hao Wen-Chao, Nie Xiao-Fen, Nie Rui, Xu Liu-de, Liu De-Fu

机构信息

College of Hydraulic and Environmental Engineering, China Three Gorges University, Yichang 443002, China.

Engineering Research Center of Eco-environment in Three Gorges Reservoir Area Region, Yichang 443002, China.

出版信息

Huan Jing Ke Xue. 2019 Jul 8;40(7):3039-3048. doi: 10.13227/j.hjkx.201811243.

Abstract

The ecological problems due to reservoir construction are causing unprecedented concern. To reveal the differences in organic carbon distribution characteristics and sediment sources of total organic carbon (TOC) between the old and new reservoirs, water samples, and sediment samples from reservoirs constructed in the three different periods of Miaowei, Gongguoqiao, and Dachaoshan were collected in November 2017. The temperature (), dissolved oxygen (DO), TOC, redox potential (ORP), total nitrogen (TN), and total phosphorus (TP) of the water samples were measured. The isotopes N and C were used as indicators with IsoSource software to analyze the contributions of TOC sources and their source materials to the corresponding reservoir sediments, in order to explore the carbon cycle mechanism and evolution mode of reservoir. The results showed that the average concentrations of organic carbon in the waters of the Miaowei, Gongguoqiao, and Dachaoshan Reservoirs were 0.95 mg·L, 1.97 mg·L, and 4.64 mg·L, respectively. The range of organic carbon content in the corresponding sediments was 4.41-81.63 g·kg, 18.30-28.42 g·kg, and 9.16-14.46 g·kg, respectively. The cascade construction of the reservoirs resulted in a difference between the sediment sources of the new and old reservoirs and the surrounding recharge area, meaning that the TOC of the new and old reservoirs were significantly different. For the TOC of waterbodies, the difference between the thermodynamic state of water and dissolved oxygen indirectly affects the distribution trend of TOC. The sediments mainly reflect the influence of source elements, that is, the ability of the sedimentary environment to preserve organic matter was the main cause of the vertical distribution of DCS, MV, and GGQ sediments. In the evolution mode of cascade reservoir, the research shows that it can be preliminarily set as three stages. Firstly, due to the short age of MV, it is in the first stage and mainly accumulates the TOC from the upstream. GGQ is longer than the age of MV, and it is mainly used to decompose the upstream TOC, so it is defined as in the second stage. Finally, as an old reservoir, DCS mainly accumulates TOC sources around the reservoir, which can be regarded as the third stage.

摘要

水库建设引发的生态问题正引起前所未有的关注。为揭示新旧水库之间有机碳分布特征及总有机碳(TOC)的沉积物来源差异,于2017年11月采集了妙味、功果桥和大朝山三个不同时期建设的水库的水样和沉积物样本。测量了水样的温度()、溶解氧(DO)、TOC、氧化还原电位(ORP)、总氮(TN)和总磷(TP)。以氮和碳同位素为指标,利用IsoSource软件分析TOC来源及其源物质对相应水库沉积物的贡献,以探究水库的碳循环机制和演化模式。结果表明,妙味、功果桥和大朝山水库水体中有机碳的平均浓度分别为0.95mg·L、1.97mg·L和4.64mg·L。相应沉积物中有机碳含量范围分别为4.41 - 81.63g·kg、18.30 - 28.42g·kg和9.16 - 14.46g·kg。水库的梯级建设导致新旧水库与周边补给区的沉积物来源存在差异,即新旧水库的TOC存在显著差异。对于水体的TOC,水的热力学状态和溶解氧之间的差异间接影响TOC的分布趋势。沉积物主要反映源元素的影响,即沉积环境保存有机质的能力是DCS、MV和GGQ沉积物垂直分布的主要原因。在梯级水库的演化模式方面,研究表明可初步设定为三个阶段。首先,由于MV建成时间短,处于第一阶段,主要积累来自上游的TOC。GGQ建成时间长于MV,主要用于分解上游的TOC,因此定义为处于第二阶段。最后,作为老水库,DCS主要积累水库周边的TOC来源,可视为第三阶段。

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