Shenzhen Grubbs Institute and Department of Chemistry, Southern University of Science and Technology, Xueyuan Blvd 1088, Shenzhen, 518055, China.
University of Jyväskylä, Department of Chemistry, P. O. Box 35, FI-40014, Jyväskylä, Finland.
Chem Commun (Camb). 2020 Jan 18;56(6):888-891. doi: 10.1039/c9cc09585c. Epub 2019 Dec 20.
A 2,3-dialkoxynaphthalene-based naphthocage has been synthesized. This naphthocage prefers to bind small organic cations with its low-symmetry conformation, which is in contrast to 2,6-dialkoxynaphthalene-based naphthocages. Self-sorting of these two naphthocages with two structurally similar guests tetramethylammonium and tetraethylammonium was achieved as well.
一种基于 2,3-二烷氧基萘的萘笼已经被合成。这种萘笼倾向于与小分子有机阳离子结合，采用低对称构象，这与基于 2,6-二烷氧基萘的萘笼不同。这两种萘笼与两个结构相似的客体四甲基铵和四乙基铵也能实现自分类。
