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杨树木片分别控温控压爆破预处理评价

Assessment on temperature-pressure severally controlled explosion pretreatment of poplar.

机构信息

Tianjin Key Laboratory of Pulp & Paper, Tianjin University of Science and Technology, Tianjin 300457, China.

Tianjin Key Laboratory of Pulp & Paper, Tianjin University of Science and Technology, Tianjin 300457, China.

出版信息

Carbohydr Polym. 2020 Feb 15;230:115622. doi: 10.1016/j.carbpol.2019.115622. Epub 2019 Nov 13.

Abstract

In this work, temperature-pressure severally controlled explosion pretreatment (TPE) was proposed to pretreat poplar chips to improve the cellulase hydrolysis yield. In TPE process, native poplar chips (NP) were mixed with steam and N under pressure of 2.6, 2.8 and 3.0 MPa at 209 °C for 7 min. Meanwhile, steam explosion (SE) was also used to pretreat poplar chips for comparison at 209 °C (1.9 MPa) for 7 min. Results showed that the contents of hemicellulose and lignin were decreased from 19.4 % to 4.6 % and from 27.8 %-19.5 % with increasing pressure, respectively. For cellulase hydrolysis process, TPE was more advantageous than SE due to lower contents of hemicellulose and lignin, resulting in a higher cellulose conversion (40.7 %) in relation to SE sample (34.9 %). The Langmuir isothermal- type equation expressed the factors related to the hydrolysis capacity, and the results showed that this model can well describe the kinetics of the enzymatic hydrolysis.

摘要

在这项工作中,分别采用温度-压力控制爆炸预处理(TPE)和蒸汽爆炸(SE)对杨木片进行预处理,以提高纤维素酶水解产量。在 TPE 过程中,将原生杨木片(NP)与蒸汽和氮气在 2.6、2.8 和 3.0 MPa 的压力下于 209°C 下混合反应 7 min。同时,也采用 SE 在 209°C(1.9 MPa)下处理杨木片作为对照,反应时间为 7 min。结果表明,随着压力的增加,半纤维素和木质素的含量分别从 19.4%降低到 4.6%和从 27.8%-19.5%。对于纤维素酶水解过程,由于 TPE 处理的杨木片中半纤维素和木质素含量较低,TPE 比 SE 更有利于水解,因此纤维素转化率(40.7%)高于 SE 样品(34.9%)。Langmuir 等温型方程表达了与水解能力相关的因素,结果表明该模型可以很好地描述酶水解的动力学。

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