High mass loading polyaniline layer anchored cellulose fibers: Enhanced interface junction for high conductivity and flame retardancy.

Novel cellulose fibers-based composite consisted of zirconium oxyhydroxide and phytic acid doped polyaniline was prepared via a two-step method of simple chemical precipitation and followed by in situ polymerization process. Cellulose fibers were firstly modified with zirconium oxyhydroxide to enhance the binding of phytic acid doped polyaniline to the surface. A compact coating of phytic doped polyaniline was developed on zirconium oxyhydroxide modified cellulose fibers through the chelating of zirconium ions to phytic acid. The resulting composite possessed a controllable mass loading of polyaniline, which could significantly improve the conductivity, flame retardancy and electrochemical stability. Therefore, the expected chelating between zirconium ions on cellulose fibers and phytic acid doped in polyaniline supported the excellent properties of the composite paper. Notably, the developed strategy is efficient, low-cost and environmental friendly, and the work opens up new doors to the development of other cellulose fibers-related interface enhancement applications.