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采用氮化诱导自成型工艺制造的铝基复合材料

Aluminum Matrix Composites Manufactured using Nitridation-Induced Self-Forming Process.

作者信息

Lee Kon-Bae, Kim Sung-Hoon, Kim Dae-Young, Cha Pil-Ryung, Kim Hae-Sung, Choi Hyun-Joo, Ahn Jae-Pyong

机构信息

School of Advanced Materials Engineering, Kookmin University, 02707, Seoul, South Korea.

Advanced Analysis Center, Korea Institute of Science and Technology (KIST), 02792, Seoul, South Korea.

出版信息

Sci Rep. 2019 Dec 31;9(1):20389. doi: 10.1038/s41598-019-56802-3.

Abstract

Conventional manufacturing processes for aluminum matrix composites (AMCs) involve complex procedures that require unique equipment and skills at each stage. This increases the process costs and limits the scope of potential applications. In this study, a simple and facile route for AMC manufacturing is developed, a mixture of Al powder and the ceramic reinforcement is simply heated under nitrogen atmosphere to produce the composite. During heating under nitrogen atmosphere, the surface modification of both Al and the reinforcement is induced by nitridation. When the oxide layer covering Al powder surface is transformed to nitrides, temperature in the local region increases rapidly, resulting in a partial melt of Al powder. The molten Al infiltrates into the empty space among Al powder and reinforcement, thereby enabling consolidation of powders without external forces. It is possible to fabricate AMCs with various types, sizes, volume fractions, and morphologies of the reinforcement. Furthermore, the manufacturing temperature can be lowered below the melting point of Al (or the solidus temperature for alloys) because of the exothermic nature of the nitridation, which prevents formation of un-wanted reactants. The relative simplicity of this process will not only provide sufficient price competitiveness for the final products but also contribute to the expansion of the application scope of AMCs.

摘要

铝基复合材料(AMC)的传统制造工艺涉及复杂的程序,每个阶段都需要独特的设备和技能。这增加了工艺成本并限制了潜在应用的范围。在本研究中,开发了一种简单易行的AMC制造路线,将铝粉和陶瓷增强体的混合物在氮气气氛下简单加热以制备复合材料。在氮气气氛下加热过程中,铝和增强体的表面改性通过氮化作用诱导产生。当覆盖在铝粉表面的氧化层转变为氮化物时,局部区域的温度迅速升高,导致铝粉部分熔化。熔融的铝渗透到铝粉和增强体之间的空隙中,从而无需外力即可实现粉末的固结。可以制造具有各种类型、尺寸、体积分数和增强体形态的AMC。此外,由于氮化作用的放热性质,制造温度可以降低到铝的熔点(或合金的固相线温度)以下,这可以防止不需要的反应物形成。该工艺相对简单,不仅会为最终产品提供足够的价格竞争力,还将有助于扩大AMC的应用范围。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2982/6938477/622f3ea55860/41598_2019_56802_Fig1_HTML.jpg

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