Peronio Angelo, Okabayashi Norio, Griesbeck Florian, Giessibl Franz
Institute of Experimental and Applied Physics, University of Regensburg, D-93053 Regensburg, Germany.
Graduate School of Natural Science and Technology, Kanazawa University, 920-1192 Ishikawa, Japan.
Rev Sci Instrum. 2019 Dec 1;90(12):123104. doi: 10.1063/1.5119888.
The combination of inelastic electron tunneling spectroscopy (IETS), also used for IET spectrum based on scanning tunneling microscopy with atomic force microscopy (AFM) enables us to measure the vibrational energies of a single molecule along with the force exerted by the tip of a microscope, which deepens our understanding on the interaction between the tip and the molecule on a surface. The resolution of IETS is a crucial factor in determining the vibrational energies of a molecule. However, radio frequency (RF) noise from the environment significantly deteriorates the resolution. We introduce an RF noise filtering technique, which enables high resolution IETS while maintaining uncompromised AFM performance, demonstrated by vibrational measurements of a CO molecule on a copper surface.
非弹性电子隧穿谱(IETS)与基于扫描隧道显微镜的IET谱以及原子力显微镜(AFM)相结合,使我们能够测量单个分子的振动能量以及显微镜尖端施加的力,这加深了我们对表面上尖端与分子之间相互作用的理解。IETS的分辨率是确定分子振动能量的关键因素。然而,来自环境的射频(RF)噪声会显著降低分辨率。我们引入了一种RF噪声过滤技术,该技术能够实现高分辨率的IETS,同时保持AFM性能不受影响,这通过对铜表面上的一氧化碳分子进行振动测量得到了证明。