Hierarchical core-shell electrode with NiWO nanoparticles wrapped MnCoO nanowire arrays on Ni foam for high-performance asymmetric supercapacitors.

Rational construction of MnCoO-based core-shell nanomaterials with distinctive and desirable architectures possesses great potential in the advanced electrode material of high-performance supercapacitors. Here, a new class of hierarchical core-shell nanowire arrays (NWAs) with a shell of NiWO nanoparticles and a core of MnCoO nanowires is reported, which can significantly improve the electrochemical energy storage properties of supercapacitors. The unique core-shell structure endows the MnCoO@NiWO NWAs electrode with a high areal specific capacitance of 5.09 F cm at a current density of 1 mA cm and a superior cyclic retention of 96% after 5000 charge-discharge cycles, which are more preferable than those of MnCoO NWAs electrode. More importantly, an aqueous electrochemical energy storage device (core-shell MnCoO@NiWO NWAs as the positive electrode and active carbon as the negative electrode, MnCoO@NiWO//AC ASC) was assembled and shows a high energy density of 0.23 mWh cm at a power density of 2.66 mW cm, and 0.09 mWh cm at 16.00 mW cm, indicating hopeful potential for practical applications. This work highlights the significance of NiWO as a shell for hierarchical core-shell nanostructures, which can further improve the electron transport characteristic of the electrode material, thereby achieving performance breakthroughs in energy storage devices.