Ecole Polytechnique Fédérale de Lausanne (EPFL), Institute of Physics Laboratory of Statistical Biophysics, 1015 Lausanne, Switzerland.
Biological Complexity Unit, Okinawa Institute of Science and Technology Graduate University, Onna, Okinawa 904-0495, Japan.
Phys Rev E. 2019 Dec;100(6-1):060102. doi: 10.1103/PhysRevE.100.060102.
Thermodynamic observables of mesoscopic systems can be expressed as integrated empirical currents. Their fluctuations are bound by thermodynamic uncertainty relations. We introduce the hyperaccurate current as the integrated empirical current with the least fluctuations in a given nonequilibrium system. For steady-state systems described by overdamped Langevin equations, we derive an equation for the hyperaccurate current by means of a variational principle. We show that the hyperaccurate current coincides with the entropy production if and only if the latter saturates the thermodynamic uncertainty relation, and it can be substantially more precise otherwise. The hyperaccurate current can be used to improve estimates of entropy production from experimental data.
介观系统的热力学可观测量可以表示为积分经验电流。它们的涨落受热力学不确定关系的限制。我们引入超精确电流作为给定非平衡系统中波动最小的积分经验电流。对于由过阻尼朗之万方程描述的稳态系统,我们通过变分原理推导出超精确电流的方程。我们表明,超精确电流与熵产生一致,当且仅当后者使热力学不确定关系饱和,否则它可以更精确。超精确电流可用于从实验数据中提高熵产生的估计。