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抛物面形貌表面的疏水性和抗污性能。

Hydrophobic and Anti-Fouling Performance of Surface on Parabolic Morphology.

机构信息

Key Laboratory of Subsurface Hydrology and Ecological Effects in Arid Region, Ministry of Education, Chang'an University, Xi'an 710054, China.

School of Water and Environment, Chang'an University, Xi'an 710054, China.

出版信息

Int J Environ Res Public Health. 2020 Jan 19;17(2):644. doi: 10.3390/ijerph17020644.

Abstract

The hydrophobicity and anti-fouling properties of materials have important application value in industrial and agricultural production and people's daily life. To study the relationship between the unit width L of the parabolic hydrophobic material and the hydrophobicity and anti-fouling properties, the rough surface structure of the parabolic with different widths was prepared by grinding with different SiC sandpapers, and further, to obtain hydrophobic materials through chemical oxidation and chemical etching, and modification with stearic acid (SA). The morphology, surface wetting and anti-fouling properties of the modified materials were characterized by SEM and contact angle measurement. The oil-water separation performance and self-cleaning performance of the materials were explored. The surface of the modified copper sheet forms a rough structure similar to a paraboloid. When ground with 1500 grit SiC sandpaper, it is more conducive to increase the hydrophobicity of the copper sheet surface and increase the contact angle of water droplets on the copper surface. Additionally, the self-cleaning and anti-fouling experiments showed that as L decreases, copper sheets were less able to stick to foreign things such as soil, and the better the self-cleaning and anti-fouling performance was. Based on the oil-water separation experiment of copper mesh, the lower L has a higher oil-water separation efficiency. The results showed that material with parabolic morphology has great self-cleaning, anti-fouling, and oil-water separation performance. The smaller the L was, the larger the contact angle and the better hydrophobic performance and self-cleaning performance were.

摘要

材料的疏水性和抗污性能在工农业生产和人们日常生活中有重要的应用价值。为了研究抛物面疏油材料单位宽度 L 与疏水性和抗污性的关系,采用不同目数 SiC 砂纸对抛物面进行打磨,制备出不同宽度的粗糙表面结构,再通过化学氧化和化学刻蚀以及硬脂酸(SA)修饰,得到具有疏油性能的材料。通过 SEM 和接触角测量对改性材料的形貌、表面润湿性和抗污性能进行了表征。探讨了材料的油水分离性能和自清洁性能。改性铜片表面形成类似抛物面的粗糙结构。用 1500 目 SiC 砂纸打磨时,更有利于提高铜片表面疏水性,增加铜片表面水滴的接触角。此外,自清洁和抗污实验表明,随着 L 的减小,铜片表面越不容易沾上泥土等外来物,自清洁和抗污性能越好。基于铜网的油水分离实验,较低的 L 具有更高的油水分离效率。结果表明,具有抛物面形态的材料具有良好的自清洁、抗污和油水分离性能。L 越小,接触角越大,疏水性和自清洁性能越好。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5326/7014390/77cc351ee683/ijerph-17-00644-g001.jpg

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