在水/乙醇混合物中合成沸石咪唑酯骨架结构-7及其乙醇诱导的可逆相变
Synthesis of Zeolitic Imidazolate Framework-7 in a Water/Ethanol Mixture and Its Ethanol-Induced Reversible Phase Transition.
作者信息
He Ming, Yao Jianfeng, Li Lunxi, Wang Kun, Chen Fanyan, Wang Huanting
机构信息
College of Science, Nanjing Forestry University, Jiangsu 210037 (P. R. China).
Department of Chemical Engineering, Monash University, Clayton, VIC 3800 (Australia).
出版信息
Chempluschem. 2013 Oct;78(10):1222-1225. doi: 10.1002/cplu.201300193. Epub 2013 Jul 11.
PMID:31986784
Abstract
Room to breathe: An efficient method for the synthesis of zeolitic imidazolate framework-7 (ZIF-7) in ethanol/water at room temperature is reported. The ZIF-7 undergoes a reverse-phase transition from large pore (lp)-phase to narrow pore (np)-phase under heat treatment and from np-phase back to lp-phase in ethanol solution.
摘要
呼吸空间
报道了一种在室温下于乙醇/水中高效合成沸石咪唑酯骨架-7（ZIF-7）的方法。ZIF-7在热处理下经历从大孔（lp）相到窄孔（np）相的逆相变，并在乙醇溶液中从np相变回lp相。
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