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采用人工辐射对商用 TiO 和 TiO 溶胶凝胶降解咖啡因的效果进行评估比较。

Assessment comparison of commercial TiO and TiO sol-gel on the degradation of caffeine using artificial radiation.

机构信息

Department of Chemical Engineering, State University of Maringá, Av. Colombo 5790, Maringá, Paraná, Brazil.

Federal University of Paraná, R. Doutor João Maximiano 456, Jandaia do Sul, Paraná, Brazil.

出版信息

Environ Sci Pollut Res Int. 2020 Jun;27(18):22155-22168. doi: 10.1007/s11356-020-07748-x. Epub 2020 Jan 29.

Abstract

The presence of endocrine disrupting compounds in water receptor bodies, such as drugs, currently has in scientific field a great focus of studies focused on advanced water treatment techniques that enable the decontamination of water sources and public supply. In this context, this study focused on the characterization and evaluation of photocatalytic activity of catalysts calcined and uncalcined synthesized TiO and the commercial sol-gel route from caffeine degradation. The photocatalysts were characterized by N physisorption, X-ray diffraction, scanning electron microscopy (SEM/EDS), photoacoustic spectroscopy, and infrared spectroscopy (FTIR). They seek to evaluate the main textural, structural, chemical, and morphological differences that the method of synthesis can promote in obtaining a titanium oxide-based catalyst. Thus, the results of this study demonstrate that the synthesis method significantly influences the activity of the materials and that calcined TiO catalyst prepared using the sol-gel method has promising photocatalytic capabilities for the elimination of drugs such as caffeine when present in wastewater.

摘要

水中受体物(如药物)中存在的内分泌干扰化合物,目前是科学领域的一个研究重点,研究方向是先进的水处理技术,以实现水源和公共供水的净化。在此背景下,本研究的重点是对合成的 TiO 和商用溶胶-凝胶路线的煅烧和未煅烧催化剂的光催化活性进行表征和评估,从咖啡因降解的角度来看。通过 N 物理吸附、X 射线衍射、扫描电子显微镜(SEM/EDS)、光声光谱和傅里叶变换红外光谱(FTIR)对光催化剂进行了表征。这些方法旨在评估合成方法可能在获得基于氧化钛的催化剂时带来的主要结构、结构、化学和形态差异。因此,这项研究的结果表明,合成方法对材料的活性有显著影响,并且使用溶胶-凝胶法制备的煅烧 TiO 催化剂在存在废水时对消除咖啡因等药物具有有前景的光催化能力。

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