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通过动态高压均质法深入了解莲籽淀粉-卵磷脂复合物的形成机制。

Insight into the formation mechanism of lotus seed starch-lecithin complexes by dynamic high-pressure homogenization.

机构信息

College of Food Science, Fujian Agriculture and Forestry University, Fuzhou 350002, China; Fujian Provincial Key Laboratory of Quality Science and Processing Technology in Special Starch, Fujian Agriculture and Forestry University, Fuzhou 350002, China.

College of Food Science, Fujian Agriculture and Forestry University, Fuzhou 350002, China.

出版信息

Food Chem. 2020 Jun 15;315:126245. doi: 10.1016/j.foodchem.2020.126245. Epub 2020 Jan 21.

Abstract

Our objective was to investigate the correlation between processing conditions and structural properties of lotus seed starch-lecithin complexes by dynamic high-pressure homogenization and explore the formation mechanism. The complexes formed with 5% lecithin at 90 MPa had the highest complex index among samples, thus protecting the integrity of the particles. The complexes inhibited the degradation of amylopectin and retrogradation of amylose, and displayed different V-, V- and A-type crystalline patterns. Additionally, the double helix structure was enhanced with increasing pressure, and the addition of lecithin contributed to the formation of single-helix amylose-lecithin complexes. These complexes prevented the single helix structure of starch to further form double helix structures, as demonstrated by visual correlation analysis. Moreover, a formation mechanism was established, and lotus seed starch-lecithin complexes with V-type crystalline were formed under appropriate conditions, but a homogenization pressure either too low or too high was not conducive to complex formation.

摘要

我们的目的是通过动态高压匀质处理来研究加工条件与莲藕淀粉-卵磷脂复合物结构特性之间的相关性,并探讨其形成机制。在 90 MPa 下,用 5%的卵磷脂形成的复合物在样品中具有最高的复合物指数,从而保护了颗粒的完整性。复合物抑制了支链淀粉的降解和直链淀粉的回生,并表现出不同的 V、V 和 A 型结晶形态。此外,随着压力的增加,双螺旋结构得到增强,并且卵磷脂的添加有助于形成单螺旋直链淀粉-卵磷脂复合物。通过直观相关分析可以看出,这些复合物阻止了淀粉的单螺旋结构进一步形成双螺旋结构。此外,还建立了一种形成机制,即在适当的条件下可以形成 V 型结晶的莲藕淀粉-卵磷脂复合物,但匀质压力过低或过高都不利于复合物的形成。

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