Nishimoto Yoshihiro, Yasuda Makoto
Department of Applied Chemistry Graduate School of Engineering, Osaka University 2-1 Yamadaoka, Suita, 565-0871, Osaka, Japan.
Chem Asian J. 2020 Mar 16;15(6):636-650. doi: 10.1002/asia.201901730. Epub 2020 Feb 18.
Organogallium and -indium compounds are useful reagents in organic synthesis because of their moderate stability, efficient reactivity and high chemoselectivity. Carbogallation and -indation of a carbon-carbon multiple bond achieves the simultaneous formation of carbon-carbon and carbon-metal bonds. Heterogallation and -indation construct carbon-heteroatom and carbon-metal bonds. Therefore, these reaction systems represent a significant synthetic method for organogalliums and -indiums. Many chemists have attempted to apply various types of unsaturated compounds such as alkynes, alkenes, and allenes to these reaction systems. This minireview provides an overview of carboindation and -gallation as well as heteroindation and -gallation.
有机镓和铟化合物因其适度的稳定性、高效的反应活性和高化学选择性，而成为有机合成中有用的试剂。碳-碳多重键的碳镓化和碳铟化可同时形成碳-碳键和碳-金属键。杂镓化和杂铟化则构建碳-杂原子键和碳-金属键。因此，这些反应体系是有机镓和铟的一种重要合成方法。许多化学家已尝试将各种类型的不饱和化合物，如炔烃、烯烃和丙二烯应用于这些反应体系。本综述概述了碳铟化和碳镓化以及杂铟化和杂镓化。
