Liu Yudong, Woerpel K A
Department of Chemistry, New York University, 100 Washington Square East, New York, NY 10003 USA.
Synthesis (Stuttg). 2023 Aug;55(15):2261-2272. doi: 10.1055/s-0042-1751362. Epub 2022 Oct 12.
Carbometallation of alkenes and alkynes are powerful carbon-carbon bond-forming reactions. The use of compounds containing bonds between carbon and group 13 elements, particularly boron and aluminum, are particularly attractive because of the versatility of subsequent transformations. Uncatalyzed carboboration and carboalumination represent less common classes of reactions. This Short Review discusses uncatalyzed carboboration and carboalumination reactions of alkenes and alkynes, including the reaction design and mechanism.
烯烃和炔烃的碳金属化反应是强大的碳-碳键形成反应。使用含有碳与第13族元素（特别是硼和铝）之间键的化合物尤其具有吸引力，因为后续转化具有多样性。无催化的碳硼化和碳铝化代表不太常见的反应类型。本短文综述讨论了烯烃和炔烃的无催化碳硼化和碳铝化反应，包括反应设计和机理。
