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基于含有智利矢车菊叶提取物的明胶、壳聚糖和/或酪蛋白酸钠的薄膜在堆肥条件下的可分解性。

Disintegrability under composting conditions of films based on gelatin, chitosan and/or sodium caseinate containing boldo-of-Chile leafs extract.

机构信息

Faculty of Animal Science and Food Engineering, University of São Paulo, Av. Duque de Caxias Norte, 225, 13635-900 Pirassununga, SP, Brazil; Food Research Center (FoRC), University of São Paulo, Rua do Lago, 250, Semi-industrial Building, Block C, 05508-080 São Paulo, SP, Brazil.

Faculty of Animal Science and Food Engineering, University of São Paulo, Av. Duque de Caxias Norte, 225, 13635-900 Pirassununga, SP, Brazil; Food Research Center (FoRC), University of São Paulo, Rua do Lago, 250, Semi-industrial Building, Block C, 05508-080 São Paulo, SP, Brazil.

出版信息

Int J Biol Macromol. 2020 May 15;151:178-185. doi: 10.1016/j.ijbiomac.2020.02.051. Epub 2020 Feb 7.

Abstract

Biodegradable films based on pure gelatin (GEL100), chitosan (CH100) and sodium caseinate (SCas100), and gelatin-chitosan (GEL50:CH50) and gelatin‑sodium caseinate (GEL50:SCas50) blends, without or with boldo-of-Chile leafs extract (BoC) were studied. The solubility in water (%) of all the pure films was analyzed. Moreover, the disintegration process was evaluated throughout the mass loss (%), structural (FTIR) changes and visual analyses of films up to 5 days of composting conditions. The Boltzmann function allowed obtaining the half-maximal disintegration time (t) of all the films. Only Scas100 films exhibited complete solubility in water, compared to the other films (P < 0.05). At day 1, SCas100 + B film exhibited total mass loss, meanwhile for the other film samples this parameter varied between 47.9 ± 3.0% (CH100 + B) and 6.8 ± 1.3% (GEL100 + B) (P < 0.05). FTIR analysis showed some changes in the intensity of the typical bands of the pure or blended films. Photographs registered exhibited the complete disintegration of all films into 5 days. Finally, Boltzmann equation displayed that pure SCas100 film disintegrated in the shortest time (0.500 days), and GEL50:CH50 blended film in the longest time (1.766 days). In conclusion, the results of this work show an appropriate and complete disintegration of all studied films in composting conditions.

摘要

研究了基于纯明胶(GEL100)、壳聚糖(CH100)和酪蛋白酸钠(SCas100)以及明胶-壳聚糖(GEL50:CH50)和明胶-酪蛋白酸钠(GEL50:SCas50)共混物的可生物降解薄膜,没有或有智利叶提取物(BoC)。分析了所有纯膜在水中的溶解度(%)。此外,通过质量损失(%)、结构(FTIR)变化和薄膜在堆肥条件下长达 5 天的视觉分析来评估崩解过程。Boltzmann 函数允许获得所有薄膜的半最大崩解时间(t)。与其他薄膜相比,只有 Scas100 薄膜在水中完全溶解(P < 0.05)。在第 1 天,SCas100 + B 薄膜表现出完全的质量损失,而对于其他薄膜样品,该参数在 47.9 ± 3.0%(CH100 + B)和 6.8 ± 1.3%(GEL100 + B)之间变化(P < 0.05)。FTIR 分析显示了纯或共混薄膜典型带的强度的一些变化。注册的照片显示所有薄膜在 5 天内完全崩解。最后,Boltzmann 方程显示纯 SCas100 薄膜在最短时间(0.500 天)内崩解,而 GEL50:CH50 共混薄膜在最长时间(1.766 天)内崩解。总之,这项工作的结果表明,所有研究的薄膜在堆肥条件下都能适当且完全崩解。

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