Faculty of Animal Science and Food Engineering, University of São Paulo, Av. Duque de Caxias Norte, 225, 13635-900 Pirassununga, SP, Brazil; Food Research Center (FoRC), University of São Paulo, Rua do Lago, 250, Semi-industrial Building, Block C, 05508-080 São Paulo, SP, Brazil.
Faculty of Animal Science and Food Engineering, University of São Paulo, Av. Duque de Caxias Norte, 225, 13635-900 Pirassununga, SP, Brazil; Food Research Center (FoRC), University of São Paulo, Rua do Lago, 250, Semi-industrial Building, Block C, 05508-080 São Paulo, SP, Brazil.
Int J Biol Macromol. 2020 May 15;151:178-185. doi: 10.1016/j.ijbiomac.2020.02.051. Epub 2020 Feb 7.
Biodegradable films based on pure gelatin (GEL100), chitosan (CH100) and sodium caseinate (SCas100), and gelatin-chitosan (GEL50:CH50) and gelatin‑sodium caseinate (GEL50:SCas50) blends, without or with boldo-of-Chile leafs extract (BoC) were studied. The solubility in water (%) of all the pure films was analyzed. Moreover, the disintegration process was evaluated throughout the mass loss (%), structural (FTIR) changes and visual analyses of films up to 5 days of composting conditions. The Boltzmann function allowed obtaining the half-maximal disintegration time (t) of all the films. Only Scas100 films exhibited complete solubility in water, compared to the other films (P < 0.05). At day 1, SCas100 + B film exhibited total mass loss, meanwhile for the other film samples this parameter varied between 47.9 ± 3.0% (CH100 + B) and 6.8 ± 1.3% (GEL100 + B) (P < 0.05). FTIR analysis showed some changes in the intensity of the typical bands of the pure or blended films. Photographs registered exhibited the complete disintegration of all films into 5 days. Finally, Boltzmann equation displayed that pure SCas100 film disintegrated in the shortest time (0.500 days), and GEL50:CH50 blended film in the longest time (1.766 days). In conclusion, the results of this work show an appropriate and complete disintegration of all studied films in composting conditions.
研究了基于纯明胶(GEL100)、壳聚糖(CH100)和酪蛋白酸钠(SCas100)以及明胶-壳聚糖(GEL50:CH50)和明胶-酪蛋白酸钠(GEL50:SCas50)共混物的可生物降解薄膜,没有或有智利叶提取物(BoC)。分析了所有纯膜在水中的溶解度(%)。此外,通过质量损失(%)、结构(FTIR)变化和薄膜在堆肥条件下长达 5 天的视觉分析来评估崩解过程。Boltzmann 函数允许获得所有薄膜的半最大崩解时间(t)。与其他薄膜相比,只有 Scas100 薄膜在水中完全溶解(P < 0.05)。在第 1 天,SCas100 + B 薄膜表现出完全的质量损失,而对于其他薄膜样品,该参数在 47.9 ± 3.0%(CH100 + B)和 6.8 ± 1.3%(GEL100 + B)之间变化(P < 0.05)。FTIR 分析显示了纯或共混薄膜典型带的强度的一些变化。注册的照片显示所有薄膜在 5 天内完全崩解。最后,Boltzmann 方程显示纯 SCas100 薄膜在最短时间(0.500 天)内崩解,而 GEL50:CH50 共混薄膜在最长时间(1.766 天)内崩解。总之,这项工作的结果表明,所有研究的薄膜在堆肥条件下都能适当且完全崩解。