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调节硫酸/硒酸乙二铵混合晶体的光学各向同性点。

Tuning the optical isotropic point of mixed crystals of ethylenediammonium sulfate/selenate.

作者信息

Tan Melissa, Martin Alexander T, Shtukenberg Alexander G, Kahr Bart

机构信息

Department of Chemistry, New York University, New York, NY 10003, USA.

出版信息

J Appl Crystallogr. 2020 Feb 1;53(Pt 1):51-57. doi: 10.1107/S1600576719015863.

DOI:10.1107/S1600576719015863
PMID:32047403
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6998771/
Abstract

In anisotropic crystals, optical isotropic points are wavelengths where linear birefringence disappears because the refractive indices for both eigenmodes are accidentally equivalent. Here, the optical isotropic point of ethylene-diammonium selenate (EDSe) is tuned by generating a solid-solution series of EDSe doped with sulfate. Mueller matrix polarimetry and single-crystal X-ray diffraction are used to correlate changes in linear birefringence with the crystal composition of EDS Se . A scheme for using mixed crystals with isotropic points as tunable birefringent optical bandpass filters is proposed and their performance is modeled.

摘要

在各向异性晶体中,光学各向同性点是指线性双折射消失的波长,因为两种本征模的折射率偶然相等。在此,通过生成掺杂硫酸盐的硒酸乙二铵(EDSe)固溶体系列来调节硒酸乙二铵(EDSe)的光学各向同性点。利用穆勒矩阵偏振测量法和单晶X射线衍射将线性双折射的变化与EDS Se的晶体组成相关联。提出了一种使用具有各向同性点的混合晶体作为可调谐双折射光学带通滤波器的方案,并对其性能进行了建模。

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本文引用的文献

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Double cone of eigendirections in optically active ethylenediammonium selenate crystals.光学活性硒酸乙二铵晶体中的双本征方向锥
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Gyration and Permittivity of Ethylenediammonium Sulfate Crystals.乙二铵硫酸盐晶体的旋光性和介电常数
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