Hydroxide Based Integrated CO Capture from Air and Conversion to Methanol.

The first example of an alkali hydroxide-based system for CO capture and conversion to methanol has been established. Bicarbonate and formate salts were hydrogenated to methanol with high yields in a solution of ethylene glycol. In an integrated one-pot system, CO was efficiently captured by an ethylene glycol solution of the base and subsequently hydrogenated to CHOH at relatively mild temperatures (100-140 °C) using Ru-PNP catalysts. The produced methanol can be easily separated by distillation. Hydroxide base regeneration at low temperatures was observed for the first time. Finally, CO capture from ambient air and hydrogenation to CHOH was demonstrated. We postulate that the high capture efficiency and stability of hydroxide bases make them superior to existing amine-based routes for direct air capture and conversion to methanol in a scalable process.