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集成式二氧化碳捕集与甲醇的一锅法生产。

Integrated CO capture and one-pot production of methanol.

作者信息

Mandal Mrinmay

机构信息

School of Chemical and Biomolecular Engineering, Georgia Institute of Technology, Atlanta, GA 30332-0100, USA.

出版信息

Dalton Trans. 2020 Dec 21;49(47):17140-17142. doi: 10.1039/d0dt03667f. Epub 2020 Nov 17.

Abstract

The capture, storage, and utilization (CSU) of CO to produce methanol which can be used as a fuel, fuel additive, and precursor in organic synthesis is an area of fascinating research. This directly influences the reduction of the CO concentration by capturing CO from industrial and automobile emissions. The development of integrated CO capture and conversion to a fuel and fuel additive has garnered considerable attention as it eliminates costly processes to produce pure CO. This contribution presents a summary of integrated CO capture and conversion to methanol (MeOH) using amine-assisted and alkali hydroxide-assisted one-pot systems. The superiority of the alkali hydroxide-based system to the amine-based system for the conversion to MeOH is systematically presented.

摘要

捕获、储存和利用一氧化碳(CO)以生产可作为燃料、燃料添加剂和有机合成前体的甲醇,是一个引人入胜的研究领域。这直接影响通过从工业和汽车排放中捕获CO来降低CO浓度。集成式CO捕获并转化为燃料和燃料添加剂的开发已引起了相当大的关注,因为它消除了生产纯CO的昂贵过程。本论文总结了使用胺辅助和碱金属氢氧化物辅助的一锅法系统将CO集成捕获并转化为甲醇(MeOH)的过程。系统地阐述了基于碱金属氢氧化物的系统在转化为MeOH方面相对于基于胺的系统的优越性。

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