Taye Mesfin Asfaw
Science Division, West Los Angeles College, 9000 Overland Ave., Culver City, California 90230, USA.
Phys Rev E. 2020 Jan;101(1-1):012131. doi: 10.1103/PhysRevE.101.012131.
The expressions for entropy production, free energy, and entropy extraction rates are derived for a Brownian particle that walks in an underdamped medium. Our analysis indicates that as long as the system is driven out of equilibrium, it constantly produces entropy at the same time it extracts entropy out of the system. At steady state, the rate of entropy production e[over ̇]{p} balances the rate of entropy extraction h[over ̇]{d}. At equilibrium both entropy production and extraction rates become zero. The entropy production and entropy extraction rates are also sensitive to time. As time progresses, both entropy production and extraction rates increase in time and saturate to constant values. Moreover, employing microscopic stochastic approach, several thermodynamic relations for different model systems are explored analytically and via numerical simulations by considering a Brownian particle that moves in overdamped medium. Our analysis indicates that the results obtained for underdamped cases quantitatively agree with overdamped cases at steady state. The fluctuation theorem is also discussed.
我们推导了在欠阻尼介质中运动的布朗粒子的熵产生、自由能和熵提取率的表达式。我们的分析表明,只要系统偏离平衡态,它就在从系统中提取熵的同时不断产生熵。在稳态下,熵产生率(\dot{e}{p})与熵提取率(\dot{h}{d})平衡。在平衡态时,熵产生率和提取率都变为零。熵产生率和熵提取率也对时间敏感。随着时间的推移,熵产生率和提取率都随时间增加并趋于恒定值。此外,采用微观随机方法,通过考虑在过阻尼介质中运动的布朗粒子,对不同模型系统的几个热力学关系进行了解析探索和数值模拟。我们的分析表明,欠阻尼情况下获得的结果在稳态下与过阻尼情况定量一致。还讨论了涨落定理。