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在温度随空间线性变化的热浴中运行的系统中,熵产生率的精确时间相关解析解。

Exact time-dependent analytical solutions for entropy production rate in a system operating in a heat bath in which temperature varies linearly in space.

作者信息

Taye Mesfin Asfaw

机构信息

West Los Angeles College, Science Division 9000 Overland Ave, Culver City, California 90230, USA.

出版信息

Phys Rev E. 2022 May;105(5-1):054126. doi: 10.1103/PhysRevE.105.054126.

Abstract

The nonequilibrium thermodynamics feature of a Brownian motor is investigated by obtaining exact time-dependent solutions. This in turn enables us to investigate not only the long time property (steady state) but also the short time the behavior of the system. The general expressions for the free energy, entropy production e[over ̇]{p}(t) as well as entropy extraction h[over ̇]{d}(t) rates are derived for a system that is genuinely driven out of equilibrium by time-independent force as well as by spatially varying thermal background. We show that for a system that operates between hot and cold reservoirs, most of the thermodynamics quantities approach a nonequilibrium steady state in the long time limit. The change in free energy becomes minimal at a steady state. However, for a system that operates in a heat bath where its temperature varies linearly in space, the entropy production and extraction rates approach a nonequilibrium steady state while the change in free energy varies linearly in space. This reveals that unlike systems at equilibrium, when systems are driven out of equilibrium, their free energy may not be minimized. The thermodynamic properties of a system that operates between the hot and cold baths are further compared and contrasted with a system that operates in a heat bath where its temperature varies linearly in space along with the reaction coordinate. We show that the entropy, entropy production, and extraction rates are considerably larger for the linearly varying temperature case than a system that operates between the hot and cold baths revealing such systems are inherently irreversible. For both cases, in the presence of load or when a distinct temperature difference is retained, the entropy S(t) monotonously increases with time and saturates to a constant value as t further steps up. The entropy production rate e[over ̇]{p} decreases in time and at steady state, e[over ̇]{p}=h[over ̇]_{d}>0, which agrees with the results shown in M. Asfaw's [Phys. Rev. E 89, 012143 (2014)1539-375510.1103/PhysRevE.89.012143; Phys. Rev. E 92, 032126 (2015)10.1103/PhysRevE.92.032126]. Moreover, the velocity, as well as the efficiency of the system that operates between the hot and cold baths, are also collated and contrasted with a system that operates in a heat bath where its temperature varies linearly in space along with the reaction coordinate. A system that operates between the hot and cold baths has significantly lower velocity but a higher efficiency in comparison with a linearly varying temperature case.

摘要

通过获得精确的时间相关解,研究了布朗马达的非平衡热力学特性。这进而使我们不仅能够研究系统的长时间性质(稳态),还能研究其短时间行为。对于一个由与时间无关的力以及空间变化的热背景真正驱动至非平衡态的系统,推导了自由能、熵产生率(\dot{e}{p}(t))以及熵提取率(\dot{h}{d}(t))的一般表达式。我们表明,对于在热库和冷库之间运行的系统,在长时间极限下,大多数热力学量趋近于非平衡稳态。在稳态时,自由能的变化最小。然而,对于在温度沿空间线性变化的热浴中运行的系统,熵产生率和提取率趋近于非平衡稳态,而自由能的变化沿空间线性变化。这表明,与处于平衡态的系统不同,当系统被驱动至非平衡态时,其自由能可能不会最小化。进一步比较和对比了在热浴和冷库之间运行的系统与在温度沿空间随反应坐标线性变化的热浴中运行的系统的热力学性质。我们表明,对于温度线性变化的情况,熵、熵产生率和提取率比在热浴和冷库之间运行的系统大得多,这表明此类系统本质上是不可逆的。对于这两种情况,在存在负载或保持明显温差时,熵(S(t))随时间单调增加,并在(t)进一步增大时饱和到一个恒定值。熵产生率(\dot{e}{p})随时间减小,在稳态时,(\dot{e}{p}=\dot{h}_{d}>0),这与M. Asfaw的结果一致[《物理评论E》89, 012143 (2014)1539 - 375510.1103/PhysRevE.89.012143;《物理评论E》92, 032126 (2015)10.1103/PhysRevE.92.032126]。此外,还整理和对比了在热浴和冷库之间运行的系统与在温度沿空间随反应坐标线性变化的热浴中运行的系统的速度和效率。与温度线性变化的情况相比,在热浴和冷库之间运行的系统速度明显较低,但效率较高。

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