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采用改进的渗流辅助树脂膜灌注法制备玻璃纤维增强复合材料上的石墨烯涂层及其摩擦学研究

Preparation and Tribological Study of Graphene Coating on Glass Fiber-Reinforced Composite Using Modified Percolating-Assisted Resin Film Infusion Method.

作者信息

Wang Ben, Han Wei, Ming Yueke, Zhang Xiaohui, Zhu Yansong, Duan Yugang, Wang Hongxiao, Zhao Hongying

机构信息

State Key Lab for Manufacturing Systems Engineering, Xi'an Jiaotong University, Xi'an, Shaanxi Province, 710049, China.

Polymer materials and plastics technology, Clausthal University of Technology, 38678 Clausthal-Zellerfeld, Germany.

出版信息

Materials (Basel). 2020 Feb 13;13(4):851. doi: 10.3390/ma13040851.

Abstract

Tribological properties of glass fiber-reinforced polymer (GFRP) composites used in reciprocating contact should be improved to secure the efficiency and safety because of risks of abrasion, adhesion, and fatigue deficiency amidst fiber, matrix, or interphase. This paper investigates the influence of graphene reinforcement on the wear resistance of a GFRP composite. Graphene was integrated into a typical GFRP composite as the surface coating using a modified resin film infusion method with the percolating paper assisted. Dry reciprocating sliding tests were performed against a stainless steel ball moving in a direction 45 degrees to the fiber orientation. The morphology of the worn surface was observed, and the corresponding wear mechanisms are discussed. Results suggest that the prepared graphene coating improves the wear resistance of the GFRP composite. The protected GFRP laminates remained intact during the first 20 min of the wear test and only a small fraction of fibers were broken after 60 min test. Furthermore, abrasive debris and fiber breaks originating from composite were markedly reduced, likely owing to the formation of a protective transfer film between the surface of the modified composite and the rubbing counterpart.

摘要

由于在纤维、基体或界面之间存在磨损、粘附和疲劳不足的风险,用于往复接触的玻璃纤维增强聚合物(GFRP)复合材料的摩擦学性能应得到改善,以确保效率和安全性。本文研究了石墨烯增强对GFRP复合材料耐磨性的影响。采用改进的树脂膜灌注法并借助渗滤纸,将石墨烯作为表面涂层整合到典型的GFRP复合材料中。针对在与纤维取向成45度方向移动的不锈钢球进行了干式往复滑动试验。观察了磨损表面的形貌,并讨论了相应的磨损机制。结果表明,制备的石墨烯涂层提高了GFRP复合材料的耐磨性。在磨损试验的前20分钟内,受保护的GFRP层压板保持完好,在60分钟试验后只有一小部分纤维断裂。此外,源自复合材料的磨料碎屑和纤维断裂明显减少,这可能是由于在改性复合材料表面和摩擦副之间形成了保护性转移膜。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c202/7079621/80af7f8f7f1c/materials-13-00851-g001.jpg

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