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拉曼光谱分析数据的自适应压缩感知在判别任务中的应用。

Adaptive compressed sensing of Raman spectroscopic profiling data for discriminative tasks.

机构信息

School of Management and E-Business, Zhejiang Gongshang University, Hangzhou, 310018, China; School of Information Sciences, University of Illinois at Urbana Champaign, Champaign, IL, 61820-6211, USA.

School of Management Science and Engineering, Nanjing University of Finance and Economics, Nanjing, 210023, China.

出版信息

Talanta. 2020 May 1;211:120681. doi: 10.1016/j.talanta.2019.120681. Epub 2019 Dec 28.

DOI:10.1016/j.talanta.2019.120681
PMID:32070569
Abstract

Raman spectroscopy is widely used in discriminative tasks. It provides a wide-range physio-chemical fingerprint in a rapid and non-invasive way. The Raman spectrometry uses a sensor array to convert photon signals into digital spectroscopic data. This analog-to-digital process can benefit from the compressed sensing (CS) technique. The major benefits include less memory usage, shorter acquisition time, and more cost-efficient sensor. Traditional compressed sensing and reconstruction is a series of mathematical operations performed on the signal. Meanwhile, for discriminative tasks, both the signal and the categorical information are involved. For such scenarios, this paper proposes a method that uses both domain signal and categorical information to optimize CS hyper-parameters, including 1) the sampling ratio or the sensing matrix, 2) the basis matrix for the sparse transform, and 3) the regularization rate or shrinkage factor for L1-norm minimization. A case study of formula milk brand identification proves the proposed method can generate effective compressed sensing while preserving enough discriminative power in the reconstructed signal. Under the optimized hyper-parameters, a 100% classification accuracy is retained by only sampling 20% of the original signal.

摘要

拉曼光谱广泛应用于判别任务。它提供了一种快速、非侵入式的广泛的物理化学指纹。拉曼光谱仪使用传感器阵列将光子信号转换为数字光谱数据。这种模拟到数字的过程可以受益于压缩感知(CS)技术。主要优点包括更少的内存使用、更短的采集时间和更具成本效益的传感器。传统的压缩感知和重建是对信号执行的一系列数学操作。同时,对于判别任务,信号和类别信息都涉及到。针对这种情况,本文提出了一种使用域信号和类别信息来优化 CS 超参数的方法,包括 1)采样率或传感矩阵,2)稀疏变换的基矩阵,3)L1 范数最小化的正则化率或收缩因子。配方奶品牌识别的案例研究证明,所提出的方法可以在保持重构信号足够判别能力的同时生成有效的压缩感知。在优化的超参数下,仅对原始信号的 20%进行采样即可保留 100%的分类准确性。

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引用本文的文献

1
Task-adaptive eigenvector-based projection (EBP) transform for compressed sensing: A case study of spectroscopic profiling sensor.用于压缩感知的基于任务自适应特征向量的投影(EBP)变换:光谱分析传感器的案例研究
Anal Sci Adv. 2021 Jun 29;3(1-2):29-37. doi: 10.1002/ansa.202100018. eCollection 2022 Feb.
2
Polyvinyl alcohol-based hydrogel sorbent for extraction of parabens in human milk samples by in-tube SPME-LC-UV.基于聚乙烯醇的水凝胶吸附剂,用于通过管内固相微萃取-液相色谱-紫外检测法提取人乳样品中的对羟基苯甲酸酯。
Anal Bioanal Chem. 2023 Jul;415(18):4277-4288. doi: 10.1007/s00216-022-04481-x. Epub 2022 Dec 16.
3
The statistical fusion identification of dairy products based on extracted Raman spectroscopy.
基于提取的拉曼光谱的乳制品统计融合识别
RSC Adv. 2020 Aug 11;10(50):29682-29687. doi: 10.1039/d0ra06318e. eCollection 2020 Aug 10.