Chemistry, School of Science, University of New South Wales Canberra, Australian Defence Force Academy, Canberra, ACT 2600, Australia.
Chem Commun (Camb). 2020 Feb 28;56(17):2529-2537. doi: 10.1039/c9cc07233k. Epub 2020 Feb 19.
Cucurbituril analogues can bear some of the chemical and physical characteristics of their parental origin and are derived wholly or in part from glycolurils (including homologues). The development of analogues is discussed from their earliest origins to the most recent developments, which includes deviations in binding properties and the inclusion of alternative molecular units in conjunction with glycolurils. Examples of alternative guest binding are discussed and compared to the behaviour of conventional cucurbituril.
瓜环类似物可以具有其母体的部分化学和物理特性,并且完全或部分衍生自乙二醛(包括同系物)。本文从最早的起源到最近的发展讨论了类似物的发展,包括结合特性的偏差以及与乙二醛一起包含替代分子单元。讨论了替代客体结合的实例,并与常规瓜环的行为进行了比较。