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使用由半不稳定和非惰性配体支撑的镍配合物进行光催化和电催化制氢。

Photocatalytic and electrocatalytic hydrogen production using nickel complexes supported by hemilabile and non-innocent ligands.

作者信息

Inoue Satoshi, Yan Yin-Nan, Yamanishi Katsunori, Kataoka Yusuke, Kawamoto Tatsuya

机构信息

Department of Chemistry, Faculty of Science, Kanagawa University, 2946 Tsuchiya, Hiratsuka, 259-1293, Japan.

Department of Chemistry, Graduate School of Natural Science and Technology, Shimane University, 1060 Nishikawatsu, Matsue, 690-8504, Japan.

出版信息

Chem Commun (Camb). 2020 Mar 5;56(19):2829-2832. doi: 10.1039/c9cc09568c.

DOI:10.1039/c9cc09568c
PMID:32073053
Abstract

Nickel complexes with non-innocent ligands generated by one-electron reduction of octahedral Schiff base nickel(ii) complexes with hemilabile ligands exhibited excellent catalytic activities of over 5000 TONs through a metal-ligand cooperation mechanism for hydrogen evolution from water under visible light irradiation.

摘要

通过对具有半不稳定配体的八面体席夫碱镍（II）配合物进行单电子还原生成的含非惰性配体的镍配合物，在可见光照射下通过金属-配体协同机制从水中析氢表现出超过5000个TONs的优异催化活性。

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