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钛铁矿泥废料作为混凝土添加剂的应用。

Application of Ilmenite Mud Waste as an Addition to Concrete.

作者信息

Chyliński Filip, Kuczyński Krzysztof, Łukowski Paweł

机构信息

Instytut Techniki Budowlanej, 00-611 Warsaw, Poland.

Warsaw University of Technology, Faculty of Civil Engineering, 00-637 Warsaw, Poland.

出版信息

Materials (Basel). 2020 Feb 14;13(4):866. doi: 10.3390/ma13040866.

DOI:10.3390/ma13040866
PMID:32075138
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7079594/
Abstract

Storing waste in concrete instead of landfills is environmentally friendly and also might make concrete more sustainable if some part is replaced with cement This article presents a new way of valorising hazardous waste, namely ilmenite MUD from the production of titanium dioxide, which is used as a reactive additive to concrete. In fact, there are currently no articles presenting the way of valorisation that is presented in this paper. The global annual production of MUD is estimated to be about 0.7 million tons. Valorisation is possible due to the additional rinsing and filtering in the factory, which also confirms the novelty of this article. In this operation, the most hazardous compounds are returned back to the factory process. Rinsed mud (RMUD) is a pozzolanic reactive material with the potential use as a substitute of a part of Portland cement in concrete and other cementitious binders, like siliceous fly ash (FA). The level of RMUD pozzolanic activity is as high as the activity of siliceous fly ash. Comparative tests of concretes containing RMUD and fly ash, such as compressive strength, bending strength and shrinkage, were conducted. The concrete containing RMUD reached almost 90% of compressive and 108% of bending strength after 28 days of curing, compared to FA concrete. The results presented in this article are very promising and might point to a new way of valorising ilmenite mud waste.

摘要

将废物储存在混凝土中而非垃圾填埋场不仅环保,而且如果部分水泥被替代,还可能使混凝土更具可持续性。本文提出了一种利用危险废物的新方法,即将二氧化钛生产过程中产生的钛铁矿泥用作混凝土的活性添加剂。事实上,目前尚无文章介绍本文所提出的这种利用方式。据估计,全球每年的钛铁矿泥产量约为70万吨。由于工厂额外的冲洗和过滤,使得这种利用成为可能,这也证实了本文的新颖性。在这个过程中,最危险的化合物被返回工厂流程。冲洗后的泥浆(RMUD)是一种火山灰活性材料,有潜力替代混凝土和其他胶凝材料(如硅灰)中的部分波特兰水泥。RMUD的火山灰活性水平与硅灰相当。对含有RMUD和粉煤灰的混凝土进行了抗压强度、抗弯强度和收缩等对比试验。与含粉煤灰的混凝土相比,含RMUD的混凝土在养护28天后,抗压强度达到了近90%,抗弯强度达到了108%。本文给出的结果非常有前景,可能为钛铁矿泥废物的利用指明一条新途径。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ff7d/7079594/75b3aa2dad88/materials-13-00866-g016.jpg
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本文引用的文献

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Life Cycle Assessment of Completely Recyclable Concrete.完全可回收混凝土的生命周期评估
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2
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J Environ Manage. 2013 Oct 15;128:625-30. doi: 10.1016/j.jenvman.2013.06.015. Epub 2013 Jul 8.
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Use of selected waste materials in concrete mixes.混凝土混合料中选定废料的使用。
含氨粉煤灰:水泥基复合材料中氨的性质与排放
Materials (Basel). 2021 Feb 3;14(4):707. doi: 10.3390/ma14040707.
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Effects of Elevated Temperatures on the Properties of Cement Mortars with the Iron Oxides Concentrate.高温对含氧化铁精矿水泥砂浆性能的影响。
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Undissolved Ilmenite Mud from TiO Production-Waste or a Valuable Addition to Portland Cement Composites?来自钛白粉生产废料的未溶解钛铁矿泥浆——是波特兰水泥复合材料的宝贵添加剂吗?
Materials (Basel). 2020 Aug 12;13(16):3555. doi: 10.3390/ma13163555.
6
Ilmenite Mud Waste as an Additive for Frost Resistance in Sustainable Concrete.钛铁矿泥废料作为可持续混凝土抗冻性的添加剂
Materials (Basel). 2020 Jun 28;13(13):2904. doi: 10.3390/ma13132904.
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