Chyliński Filip, Kuczyński Krzysztof, Łukowski Paweł
Instytut Techniki Budowlanej, 00-611 Warsaw, Poland.
Warsaw University of Technology, Faculty of Civil Engineering, 00-637 Warsaw, Poland.
Materials (Basel). 2020 Feb 14;13(4):866. doi: 10.3390/ma13040866.
Storing waste in concrete instead of landfills is environmentally friendly and also might make concrete more sustainable if some part is replaced with cement This article presents a new way of valorising hazardous waste, namely ilmenite MUD from the production of titanium dioxide, which is used as a reactive additive to concrete. In fact, there are currently no articles presenting the way of valorisation that is presented in this paper. The global annual production of MUD is estimated to be about 0.7 million tons. Valorisation is possible due to the additional rinsing and filtering in the factory, which also confirms the novelty of this article. In this operation, the most hazardous compounds are returned back to the factory process. Rinsed mud (RMUD) is a pozzolanic reactive material with the potential use as a substitute of a part of Portland cement in concrete and other cementitious binders, like siliceous fly ash (FA). The level of RMUD pozzolanic activity is as high as the activity of siliceous fly ash. Comparative tests of concretes containing RMUD and fly ash, such as compressive strength, bending strength and shrinkage, were conducted. The concrete containing RMUD reached almost 90% of compressive and 108% of bending strength after 28 days of curing, compared to FA concrete. The results presented in this article are very promising and might point to a new way of valorising ilmenite mud waste.
将废物储存在混凝土中而非垃圾填埋场不仅环保,而且如果部分水泥被替代,还可能使混凝土更具可持续性。本文提出了一种利用危险废物的新方法,即将二氧化钛生产过程中产生的钛铁矿泥用作混凝土的活性添加剂。事实上,目前尚无文章介绍本文所提出的这种利用方式。据估计,全球每年的钛铁矿泥产量约为70万吨。由于工厂额外的冲洗和过滤,使得这种利用成为可能,这也证实了本文的新颖性。在这个过程中,最危险的化合物被返回工厂流程。冲洗后的泥浆(RMUD)是一种火山灰活性材料,有潜力替代混凝土和其他胶凝材料(如硅灰)中的部分波特兰水泥。RMUD的火山灰活性水平与硅灰相当。对含有RMUD和粉煤灰的混凝土进行了抗压强度、抗弯强度和收缩等对比试验。与含粉煤灰的混凝土相比,含RMUD的混凝土在养护28天后,抗压强度达到了近90%,抗弯强度达到了108%。本文给出的结果非常有前景,可能为钛铁矿泥废物的利用指明一条新途径。