Department of Chemistry, North Carolina State University, Raleigh, NC 27695-8204, USA.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China.
Molecules. 2020 Feb 16;25(4):867. doi: 10.3390/molecules25040867.
The onsite repulsion, spin-orbit coupling and polarizability of elements and their ions play important roles in controlling the physical properties of molecules and condensed materials. In celebration of the 150th birthday of the periodic table this year, we briefly review how these parameters affect the physical properties and are interrelated.
元素及其离子的现场排斥、自旋轨道耦合和极化率在控制分子和凝聚态材料的物理性质方面起着重要作用。值此元素周期表诞生 150 周年之际,我们简要回顾了这些参数如何影响物理性质以及它们之间的相互关系。