Zhang Feilong, Fan Jun-Bing, Wang Shutao
CAS Key Laboratory of Bio-inspired Materials and Interfacial Science, CAS Center for Excellence in Nanoscience, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. R. China.
University of Chinese Academy of Sciences, Beijing, 100049, P. R. China.
Angew Chem Int Ed Engl. 2020 Dec 1;59(49):21840-21856. doi: 10.1002/anie.201916473. Epub 2020 Sep 13.
Interfacial polymerization, where a chemical reaction is confined at the liquid-liquid or liquid-air interface, exhibits a strong advantage for the controllable fabrication of films, capsules, and fibers for use as separation membranes and electrode materials. Recent developments in technology and polymer chemistry have brought new vigor to interfacial polymerization. Here, we consider the history of interfacial polymerization in terms of the polymerization types: interfacial polycondensation, interfacial polyaddition, interfacial oxidative polymerization, interfacial polycoordination, interfacial supramolecular polymerization, and some others. The accordingly emerging functional materials are highlighted, as well as the challenges and opportunities brought by new technologies for interfacial polymerization. Interfacial polymerization will no doubt keep on developing and producing a series of fascinating functional materials.
界面聚合是指化学反应局限于液-液或液-气界面，在可控制备用作分离膜和电极材料的薄膜、胶囊和纤维方面具有显著优势。技术和高分子化学的最新发展为界面聚合带来了新的活力。在此，我们从聚合类型的角度来审视界面聚合的历史：界面缩聚、界面加聚、界面氧化聚合、界面配位聚合、界面超分子聚合等等。文中重点介绍了相应出现的功能材料，以及界面聚合新技术带来的挑战和机遇。界面聚合无疑将持续发展并生产出一系列引人入胜的功能材料。
