• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

在基于乙酸、TS-1和过氧化氢的简单催化剂体系存在下，糠醛和呋喃衍生物氧化生成马来酸。

Oxidation of Furfural and Furan Derivatives to Maleic Acid in the Presence of a Simple Catalyst System Based on Acetic Acid and TS-1 and Hydrogen Peroxide.

作者信息

Lou Yuzhen, Marinkovic Sinisa, Estrine Boris, Qiang Wei, Enderlin Gérald

机构信息

Transformations Intégrées de la Matière Renouvelable, ESCOM, UTC, EA 4297 TIMR, 1 allée du réseau Jean-Marie Buckmaster, 60200 Compiègne, France.

Green Chemistry Department, Agro-industrie Recherches et Développements, Route de Bazancourt, 51110 Pomacle, France.

出版信息

ACS Omega. 2020 Feb 10;5(6):2561-2568. doi: 10.1021/acsomega.9b02141. eCollection 2020 Feb 18.

DOI:10.1021/acsomega.9b02141
PMID:32095680
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7033676/
Abstract

Titanium silicate molecular sieve (TS-1) and acetic acid efficiently catalyze the oxidation of furan and furan derivatives to the corresponding maleic acid (MA) in very good yields using hydrogen peroxide as an oxidizing agent. The effect of various solvents, the effect of temperature, reaction time, concentration of hydrogen peroxide, and quantities of the catalyst on the MA yield was studied. With the best conditions, MA is the sole product obtained after a fast and simple purification by filtration and evaporation. Compared to the previously reported methods, this work is a good compromise between the different reaction parameters and offers a good alternative to the production of biosourced MA.

摘要

钛硅分子筛（TS-1）和乙酸以过氧化氢为氧化剂，能高效地将呋喃及其衍生物氧化为相应的马来酸（MA），产率很高。研究了各种溶剂、温度、反应时间、过氧化氢浓度和催化剂用量对马来酸产率的影响。在最佳条件下，经过快速简单的过滤和蒸发纯化后，得到的唯一产物就是马来酸。与先前报道的方法相比，本研究在不同反应参数之间取得了良好的平衡，为生物源马来酸的生产提供了一个很好的替代方案。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d4e9/7033676/451b6851c35f/ao9b02141_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d4e9/7033676/c5c021b71278/ao9b02141_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d4e9/7033676/cd0b0ef25324/ao9b02141_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d4e9/7033676/6c6b1dd8ec43/ao9b02141_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d4e9/7033676/fb73350db89d/ao9b02141_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d4e9/7033676/6fbcdd5abcb8/ao9b02141_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d4e9/7033676/247db4443bf2/ao9b02141_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d4e9/7033676/451b6851c35f/ao9b02141_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d4e9/7033676/c5c021b71278/ao9b02141_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d4e9/7033676/cd0b0ef25324/ao9b02141_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d4e9/7033676/6c6b1dd8ec43/ao9b02141_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d4e9/7033676/fb73350db89d/ao9b02141_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d4e9/7033676/6fbcdd5abcb8/ao9b02141_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d4e9/7033676/247db4443bf2/ao9b02141_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d4e9/7033676/451b6851c35f/ao9b02141_0007.jpg

相似文献

1
Oxidation of Furfural and Furan Derivatives to Maleic Acid in the Presence of a Simple Catalyst System Based on Acetic Acid and TS-1 and Hydrogen Peroxide.在基于乙酸、TS-1和过氧化氢的简单催化剂体系存在下，糠醛和呋喃衍生物氧化生成马来酸。
ACS Omega. 2020 Feb 10;5(6):2561-2568. doi: 10.1021/acsomega.9b02141. eCollection 2020 Feb 18.
2
Factors influencing catalytic wet peroxide oxidation of maleic acid in aqueous phase over copper/micelle templated silica-3-aminopropyltrimethoxysilane catalyst.影响铜/胶束模板化硅-3-氨丙基三甲氧基硅烷催化剂在水相中催化湿过氧氧化马来酸的因素。
Water Sci Technol. 2009;60(10):2621-7. doi: 10.2166/wst.2009.528.
3
Hydrogen Peroxide Oxygenation of Furan-2-carbaldehyde via an Easy, Green Method.通过一种简单、绿色的方法对糠醛-2-甲醛进行双氧水氧化。
J Agric Food Chem. 2019 Mar 20;67(11):3114-3117. doi: 10.1021/acs.jafc.8b06284. Epub 2019 Mar 7.
4
Selective conversion of furfural to maleic anhydride and furan with VO(x)/Al(2)O(3) catalysts.用 VO(x)/Al(2)O(3) 催化剂选择性地将糠醛转化为马来酸酐和呋喃。
ChemSusChem. 2012 Oct;5(10):1984-90. doi: 10.1002/cssc.201200167. Epub 2012 Jul 30.
5
Robust selenium-doped carbon nitride nanotubes for selective electrocatalytic oxidation of furan compounds to maleic acid.用于将呋喃化合物选择性电催化氧化为马来酸的稳健的硒掺杂氮化碳纳米管。
Chem Sci. 2021 Apr 1;12(18):6342-6349. doi: 10.1039/d1sc01231b.
6
The Studies on α-Pinene Oxidation over the TS-1. The Influence of the Temperature, Reaction Time, Titanium and Catalyst Content.TS-1上α-蒎烯氧化的研究。温度、反应时间、钛含量及催化剂含量的影响。
Materials (Basel). 2021 Dec 16;14(24):7799. doi: 10.3390/ma14247799.
7
Highly Efficient Gas-Phase Oxidation of Renewable Furfural to Maleic Anhydride over Plate Vanadium Phosphorus Oxide Catalyst.高效气相氧化可再生糠醛为马来酸酐的片状钒磷氧化物催化剂。
ChemSusChem. 2018 Feb 9;11(3):612-618. doi: 10.1002/cssc.201701866. Epub 2018 Jan 9.
8
Recyclable anhydride catalyst for HO oxidation: -oxidation of pyridine derivatives.用于HO氧化的可回收酸酐催化剂：吡啶衍生物的氧化
RSC Adv. 2020 Mar 3;10(15):9165-9171. doi: 10.1039/d0ra00265h. eCollection 2020 Feb 27.
9
Direct Catalytic Conversion of Furfural to Furan-derived Amines in the Presence of Ru-based Catalyst.在 Ru 基催化剂存在下，将糠醛直接催化转化为呋喃衍生的胺。
ChemSusChem. 2020 Apr 7;13(7):1699-1704. doi: 10.1002/cssc.202000003. Epub 2020 Feb 18.
10
[The catalytic wet air oxidation reaction of acetic acid with Ti-Ce series catalyst].[钛铈系催化剂催化乙酸的湿式空气氧化反应]
Huan Jing Ke Xue. 2002 Jan 30;23(1):54-7.

引用本文的文献

1
Sustainable carbon-based catalysts for oxygen reduction-enhanced FDCA production at ultra-low cell voltage.用于在超低电池电压下氧还原增强生产FDCA的可持续碳基催化剂。
RSC Adv. 2025 Jun 30;15(28):22202-22215. doi: 10.1039/d5ra02265g.
2
Diels-Alder Cycloaddition of 2,5-Bis(hydroxymethyl)furan (BHMF) and -Phenylmaleimide Derivatives.2,5-双（羟甲基）呋喃（BHMF）与-苯基马来酰亚胺衍生物的狄尔斯-阿尔德环加成反应
ACS Omega. 2024 Aug 14;9(34):36380-36388. doi: 10.1021/acsomega.4c03804. eCollection 2024 Aug 27.
3
Mechanism and dynamics of Baeyer-Villiger oxidation of furfural to maleic anhydride in presence of HO and Au clusters.

本文引用的文献

1
Lipase-Catalyzed Baeyer-Villiger Oxidation of Cellulose-Derived Levoglucosenone into (S)-γ-Hydroxymethyl-α,β-Butenolide: Optimization by Response Surface Methodology.脂肪酶催化纤维素衍生的左旋葡萄糖酮进行拜耳-维利格氧化反应生成(S)-γ-羟甲基-α,β-丁烯内酯：基于响应面法的优化
Front Chem. 2016 Apr 19;4:16. doi: 10.3389/fchem.2016.00016. eCollection 2016.
2
Selective conversion of furfural to maleic anhydride and furan with VO(x)/Al(2)O(3) catalysts.用 VO(x)/Al(2)O(3) 催化剂选择性地将糠醛转化为马来酸酐和呋喃。
ChemSusChem. 2012 Oct;5(10):1984-90. doi: 10.1002/cssc.201200167. Epub 2012 Jul 30.
3
Reactivity of Ti(IV) species hosted in TS-1 towards H2O2-H2O solutions investigated by ab initio cluster and periodic approaches combined with experimental XANES and EXAFS data: a review and new highlights.
在HO和Au团簇存在下糠醛Baeyer-Villiger氧化制顺丁烯二酸酐的机理与动力学
J Mol Model. 2023 Nov 4;29(11):359. doi: 10.1007/s00894-023-05764-5.
4
Microwave-Assisted Lignin Wet Peroxide Oxidation to C Dicarboxylic Acids.微波辅助木质素湿式过氧化氢氧化制备二元羧酸
Ind Eng Chem Res. 2022 Mar 16;61(10):3570-3581. doi: 10.1021/acs.iecr.1c05004. Epub 2022 Mar 4.
5
Catalytic Enhancement of Cyclohexene Hydration by Ga-Doped ZSM-5 Zeolites.镓掺杂ZSM-5沸石对环己烯水合反应的催化增强作用。
ACS Omega. 2022 Jul 19;7(30):26289-26297. doi: 10.1021/acsomega.2c02031. eCollection 2022 Aug 2.
6
Recent advances in the conversion of furfural into bio-chemicals through chemo- and bio-catalysis.糠醛通过化学催化和生物催化转化为生物化学品的最新进展。
RSC Adv. 2021 Aug 9;11(43):27042-27058. doi: 10.1039/d1ra04633k. eCollection 2021 Aug 2.
7
Robust selenium-doped carbon nitride nanotubes for selective electrocatalytic oxidation of furan compounds to maleic acid.用于将呋喃化合物选择性电催化氧化为马来酸的稳健的硒掺杂氮化碳纳米管。
Chem Sci. 2021 Apr 1;12(18):6342-6349. doi: 10.1039/d1sc01231b.
8
In Situ Hydrogen Peroxide Production for Selective Oxidation of Benzyl Alcohol over a Pd@Hierarchical Titanium Silicalite Catalyst.钯负载型分级结构钛硅分子筛催化剂上原位生成过氧化氢用于苯甲醇的选择性氧化
ACS Omega. 2020 Jun 28;5(27):16865-16874. doi: 10.1021/acsomega.0c02065. eCollection 2020 Jul 14.
通过从头算簇方法和周期性方法结合实验XANES和EXAFS数据研究TS-1中Ti(IV)物种对H2O2-H2O溶液的反应性：综述与新亮点
Phys Chem Chem Phys. 2007 Sep 21;9(35):4854-78. doi: 10.1039/b706637f. Epub 2007 Jul 25.