Ultrasonication construction of the nano-petal NiCoFe-layered double hydroxide: An excellent water oxidation electrocatalyst.

Unlike other preparation methods of NiCoFe-layered double hydroxides, the present study provides a facile ultrasound method for synthesis of the nano-petal NiCoFe-layered double hydroxide (LDH) prepared under intensification frequency of 40 kHz and ultrasonic power of 305 W. The effect of time reaction on the morphology of NiCoFe-LDH was investigated using the Field Emission-Scanning Electron Microscopy images. The results show that time reaction can affect the morphology and it also showed that the optimal time for synthesis of nano-petal NiCoFe-LDH was 60 min. Then, the effect of nano-petal NiCoFe-LDH on oxygen evaluation reaction activity was studied and compared with NiCoFe-LDH-c nano paricles. Also, in order to study the effect of Co of nano-petal NiCoFe-LDH at water oxidation, the activity of NiFe-LDH synthesized in the same conditions was investigated. The results show that nano-petal NiCoFe-LDH has low onset potential (0.46 V vs. SCE), overpotential (~227 mV) and Tafel slope (234 mV per decade) in comparison with other NiCoFe-LDH nanoparticles (synthesis using co-precipitation method and ultrasonication method within 30 and 120 min), and NiFe-LDH. Based on the obtained results, the nano-petal NiCoFe-LDH can be as a suitable electrocatalyst with good stability for water oxidation reaction in the present 0.1 M KOH media.