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嵌入自适应TPX™聚合物支架中的锂-铼碳化物的稳定性增强

Enhanced Stability of Li-RHC Embedded in an Adaptive TPX™ Polymer Scaffold.

作者信息

Le Thi Thu, Pistidda Claudio, Abetz Clarissa, Georgopanos Prokopios, Garroni Sebastiano, Capurso Giovanni, Milanese Chiara, Puszkiel Julián, Dornheim Martin, Abetz Volker, Klassen Thomas

机构信息

Institute of Materials Research, Materials Technology, Helmholtz-Zentrum Geesthacht GmbH, Max-Planck-Strasse 1, D-21502 Geesthacht, Schleswig-Holstein, Germany.

Institute of Polymer Research, Helmholtz-Zentrum Geesthacht, Max-Planck-Straße 1, 21502 Geesthacht, Schleswig-Holstein, Germany.

出版信息

Materials (Basel). 2020 Feb 22;13(4):991. doi: 10.3390/ma13040991.

DOI:10.3390/ma13040991
PMID:32098426
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7078616/
Abstract

In this work, the possibility of creating a polymer-based adaptive scaffold for improving the hydrogen storage properties of the system 2LiH+MgB+7.5(3TiCl·AlCl) was studied. Because of its chemical stability toward the hydrogen storage material, poly(4-methyl-1-pentene) or in-short TPX was chosen as the candidate for the scaffolding structure. The composite system was obtained after ball milling of 2LiH+MgB+7.5(3TiCl·AlCl) and a solution of TPX in cyclohexane. The investigations carried out over the span of ten hydrogenation/de-hydrogenation cycles indicate that the material containing TPX possesses a higher degree of hydrogen storage stability.

摘要

在这项工作中，研究了创建一种基于聚合物的自适应支架以改善2LiH+MgB+7.5(3TiCl·AlCl)体系储氢性能的可能性。由于聚（4-甲基-1-戊烯）（简称TPX）对储氢材料具有化学稳定性，因此被选为支架结构的候选材料。2LiH+MgB+7.5(3TiCl·AlCl)与TPX在环己烷中的溶液经过球磨后得到复合体系。在十个加氢/脱氢循环过程中进行的研究表明，含有TPX的材料具有更高程度的储氢稳定性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8a74/7078616/e5171ae3ce25/materials-13-00991-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8a74/7078616/6d40ca987f03/materials-13-00991-g001.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8a74/7078616/3ebb2bee23d1/materials-13-00991-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8a74/7078616/e5171ae3ce25/materials-13-00991-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8a74/7078616/6d40ca987f03/materials-13-00991-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8a74/7078616/8bc700c1d04d/materials-13-00991-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8a74/7078616/f87eeb58d9c3/materials-13-00991-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8a74/7078616/9fc5620b3ab2/materials-13-00991-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8a74/7078616/8ad31d69ce4d/materials-13-00991-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8a74/7078616/4add32352cf4/materials-13-00991-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8a74/7078616/f94ca54df77c/materials-13-00991-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8a74/7078616/3ebb2bee23d1/materials-13-00991-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8a74/7078616/e5171ae3ce25/materials-13-00991-g009.jpg

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