Interdisciplinary Nanoscience Center (iNANO), Center for Energy Materials, Aarhus University, DK-8000, Denmark.
Nanoscale. 2011 May;3(5):2086-98. doi: 10.1039/c0nr00725k. Epub 2011 Mar 8.
The world in the 21(st) century is facing increasing challenges within the development of more environmentally friendly energy systems, sustainable and 'green chemistry' solutions for a variety of chemical and catalytic processes. Nanomaterials science is expected to contribute strongly by the development of new nanotools, e.g. for improving the performance of chemical reactions. Nanoconfinement is of increasing interest and may lead to significantly enhanced kinetics, higher degree of stability and/or more favourable thermodynamic properties. Nanoconfined chemical reactions may have a wide range of important applications in the near future, e.g. within the merging area of chemical storage of renewable energy. This review provides selected examples within nanoconfinement of hydrogen storage materials, which may serve as an inspiration for other research fields as well. Selected nanoporous materials, methods for preparation of nanoconfined systems and their hydrogen storage properties are reviewed.
21 世纪的世界在发展更环保的能源系统、各种化学和催化过程的可持续和“绿色化学”解决方案方面面临着越来越多的挑战。纳米材料科学有望通过开发新的纳米工具做出重大贡献,例如提高化学反应的性能。纳米限域受到越来越多的关注,可能导致动力学显著增强、稳定性提高和/或热力学性质更有利。纳米限域化学反应在不久的将来可能有广泛的重要应用,例如在可再生能源化学储存的融合领域。本综述提供了储氢材料纳米限域的一些实例,这些实例也可为其他研究领域提供灵感。综述了选定的纳米多孔材料、纳米限域体系的制备方法及其储氢性能。