通过分子内糖基化反应进行糖基偶氮苯大环的立体选择性合成及性质研究。
Stereoselective synthesis and properties of glycoazobenzene macrocycles through intramolecular glycosylation.
机构信息
Université Paris-Saclay, ENS Paris-Saclay, CNRS, PPSM, 61 Av. du Président Wilson, 94235 Cachan, France.
出版信息
Chem Commun (Camb). 2020 Mar 17;56(22):3261-3264. doi: 10.1039/c9cc09853d.
PMID:32101198
Abstract
An intramolecular glycosylation strategy was used to synthesize a series of new glycoazobenzene macrocycles with high α-selectivity and interesting chiroptical properties. The photoisomerization of an azobenzene template influences mainly the efficiency of the glycosylation.
摘要
采用分子内糖苷化策略，成功合成了一系列具有高α选择性和有趣手性光学性质的新型糖基偶氮苯大环。偶氮苯模板的光致异构化主要影响糖苷化的效率。
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