Université Paris-Saclay, ENS Paris-Saclay, CNRS, PPSM, 61 Av. du Président Wilson, 94235 Cachan, France.
Chem Commun (Camb). 2020 Mar 17;56(22):3261-3264. doi: 10.1039/c9cc09853d.
An intramolecular glycosylation strategy was used to synthesize a series of new glycoazobenzene macrocycles with high α-selectivity and interesting chiroptical properties. The photoisomerization of an azobenzene template influences mainly the efficiency of the glycosylation.
采用分子内糖苷化策略，成功合成了一系列具有高α选择性和有趣手性光学性质的新型糖基偶氮苯大环。偶氮苯模板的光致异构化主要影响糖苷化的效率。
