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通过AB型单体的界面自缩聚制备二维共价有机框架薄膜

2D covalent organic framework thin films via interfacial self-polycondensation of an AB type monomer.

作者信息

Zhang Bowen, Song Xiaoyu, Li Yusen, Li Yang, Peng Zhongxiang, Ye Long, Chen Long

机构信息

Department of Chemistry, Institute of Molecular Plus, Tianjin Key Laboratory of Molecular Optoelectronic Science, Tianjin University, Tianjin 300072, P. R. China.

School of Materials Science and Engineering, Tianjin University, Tianjin 300072, P. R. China.

出版信息

Chem Commun (Camb). 2020 Mar 17;56(22):3253-3256. doi: 10.1039/d0cc00758g.

Abstract

An A2B2 type monomer, 1,6-bis(4-formylphenyl)-3,8-bis(4-aminophenyl)pyrene (BFBAPy), was employed for the fabrication of continuous and highly crystalline 2D imine-linked covalent organic framework (COF) films with tunable thickness via interfacial self-polymerization. These films served as stable acidichromism sensors with rapid response, low detection limit and good repeatability.

摘要

一种A2B2型单体,1,6-双(4-甲酰基苯基)-3,8-双(4-氨基苯基)芘(BFBAPy),通过界面自聚合用于制备具有可调厚度的连续且高度结晶的二维亚胺连接共价有机框架(COF)薄膜。这些薄膜作为稳定的酸致变色传感器,具有快速响应、低检测限和良好的重复性。

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