采用单体截短策略对薄膜进行光催化功能化。
Photocatalytic functionalization of thin-layer membranes using a monomer truncation strategy.
作者信息
Vega-Fernández Jorge, Marcos Vanesa, Álvarez Jesús, Capitán María José, Fraile Alberto, Alemán José
机构信息
Departamento de Química Orgánica (Módulo 1), Facultad de Ciencias, Universidad Autónoma de Madrid 28049-Madrid Spain
Institute for Advanced Research in Chemical Sciences (IAdChem), Universidad Autónoma de Madrid 28049-Madrid Spain.
出版信息
Nanoscale Adv. 2024 Apr 24;6(12):3181-3187. doi: 10.1039/d4na00149d. eCollection 2024 Jun 11.
We present the design and synthesis of two new organic polymer films making use of a liquid-liquid interfacial amine-acid chloride polymerization strategy. One of them was additionally functionalized by the anchoring of -phenyl-phenothiazine through a monomer truncation strategy, which endowed it with photocatalytic activity. This photoactive film displays interesting luminescence phenomena that were used for the oxidation of a variety of sulphides to their corresponding sulfoxides and reduction of aryl bromines.
我们利用液-液界面胺-酰氯聚合策略展示了两种新型有机聚合物薄膜的设计与合成。其中一种通过单体截断策略锚定对苯基吩噻嗪进行了额外功能化，赋予其光催化活性。这种光活性薄膜表现出有趣的发光现象，可用于将多种硫化物氧化为相应的亚砜以及还原芳基溴。
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