一种微环境调控方法，用于增强含镧系元素的多金属氧酸盐在酮的氰硅烷化反应中的催化性能。
A micro-environment tuning approach for enhancing the catalytic capabilities of lanthanide containing polyoxometalate in the cyanosilylation of ketones.
机构信息
College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China.
出版信息
Chem Commun (Camb). 2020 Mar 31;56(26):3809-3812. doi: 10.1039/d0cc01216e.
PMID:32129778
Abstract
The as-synthesized (TBA)8H5[Nd(SiW11O39)2] manifested high catalytic activity for cyanosilylation of ketones, and its catalytic activity could be improved further through rational design of the reaction micro-environment beyond the molecular level, and the corresponding mechanism has been systematically studied.
摘要
合成的（TBA）8H5[Nd(SiW11O39)2]对酮的氰硅烷化具有很高的催化活性，并且可以通过在分子水平之外的合理设计反应微环境进一步提高其催化活性，并且已经系统地研究了相应的机理。
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