Gebze Technical University, Department of Chemistry, 41400, Gebze, Kocaeli, Turkey.
Gebze Technical University, Department of Chemistry, 41400, Gebze, Kocaeli, Turkey.
J Environ Manage. 2020 May 1;261:109911. doi: 10.1016/j.jenvman.2019.109911. Epub 2020 Mar 2.
The leaking of harmful organic liquids into water resources has had hazardous impacts on living organisms. Herein, we demonstrated the fabrication of hybrid sorbents using s-PPG and organosilane cross-linker. The final product exhibited high, quick absorption capacity, great reusability and excellent oil separation performance from wastewater. They also selectively absorb different oils from the bottom and surface of water without any capacity change, even in harsh conditions like wavy and sub-zero water environment. Experimental results demonstrated that the obtained sorbents are efficient to successfully remove oil from water surface, even at harsh conditions, and float on the water surface before and after oil sorption without any capacity loss and structural change. Simple preparation by avoiding time consuming multistep process, initiator, solvent, activator free reaction medium, high and selective sorption characteristics and great reusability could make these sorbents a promising candidate for the cleaning of water from harmful organic liquids, by absorbing them.
有害物质液体泄漏到水资源中对生物造成了危害。在此,我们展示了使用 s-PPG 和有机硅交联剂制备杂化吸附剂。最终产物表现出高、快速的吸收能力、良好的可重复使用性和优异的从废水中分离油的性能。它们还可以选择性地从水的底部和表面吸收不同的油,而不会发生任何容量变化,即使在波浪和零下等恶劣条件下也是如此。实验结果表明,所得到的吸附剂能够有效地从水面上去除油,即使在恶劣条件下也是如此,并且在吸附油前后都能浮在水面上,而不会有任何容量损失和结构变化。通过避免耗时的多步过程、引发剂、溶剂、无反应介质、高选择性和可重复使用性的简单制备,可以使这些吸附剂成为从有害有机液体中吸收有害物质来清洁水的有前途的候选物。