Yonehara Takuya, Goto Hiromasa
Department of Materials Science, Faculty of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8573, Japan.
Polymers (Basel). 2020 Mar 5;12(3):579. doi: 10.3390/polym12030579.
Polyaniline (PANI) was prepared in the presence of the acidic dye scarlet 3R. Color tuning was performed on PANI through doping-dedoping processes and by changing the solvent used during the optical absorption spectroscopic measurements. The chemical structure of the resulting polymer-dye composite was analyzed using infrared absorption spectroscopy, and it showed the occurrence of secondary doping in -cresol. The shape of the UV-Vis optical absorption spectra for the composite solution is dependent on the types of organic solvents used during the analysis, which was influenced by the conformation of PANI and the ionic interactions between PANI and scarlet 3R.
聚苯胺(PANI)是在酸性染料猩红3R存在的情况下制备的。通过掺杂-去掺杂过程以及改变光吸收光谱测量期间使用的溶剂,对聚苯胺进行了颜色调节。使用红外吸收光谱对所得聚合物-染料复合材料的化学结构进行了分析,结果表明在对甲酚中发生了二次掺杂。复合材料溶液的紫外-可见吸收光谱形状取决于分析期间使用的有机溶剂类型,这受到聚苯胺的构象以及聚苯胺与猩红3R之间离子相互作用的影响。