Uthaman Arya, Xian Guijun, Thomas Sabu, Wang Yunjia, Zheng Qiang, Liu Xiaoling
School of Civil Engineering, Harbin Institute of Technology, Harbin 150090, China.
International and Inter University Centre for Nanoscience and Nanotechnology (IIUCNN), Mahatma Gandhi University, Kerala 686560, India.
Polymers (Basel). 2020 Mar 7;12(3):614. doi: 10.3390/polym12030614.
The usage of polymer composites in various engineering fields has increased. However, the long-term service performance of such materials under aggressive conditions is still poorly understood, which limits the development of safe and economically effective designs. In this study, the aging of an epoxy resin and its carbon fiber-reinforced polymer (CFRP) composites upon immersion in water, acidic, and alkaline solutions was evaluated at different temperatures. The service life of the CFRP composites under various conditions could be predicted by the Arrhenius theory. The thermal and mechanical analysis results indicated that the CFRP composites were more vulnerable to HCl owing to the higher moisture absorption and diffusion of HCl into their cracks. The scanning electron microscopy results showed that the polymer matrix was damaged and degraded. Therefore, to allow long-term application, CFRP composites must be protected from acidic environments.
聚合物复合材料在各个工程领域的应用有所增加。然而,此类材料在苛刻条件下的长期服役性能仍未得到充分了解,这限制了安全且经济有效的设计的发展。在本研究中,评估了环氧树脂及其碳纤维增强聚合物(CFRP)复合材料在不同温度下浸泡于水、酸性和碱性溶液中的老化情况。CFRP复合材料在各种条件下的使用寿命可通过阿仑尼乌斯理论进行预测。热分析和力学分析结果表明,由于较高的吸湿率以及HCl向其裂纹中的扩散,CFRP复合材料更容易受到HCl的影响。扫描电子显微镜结果显示聚合物基体受到了破坏和降解。因此,为实现长期应用,CFRP复合材料必须免受酸性环境的影响。