Hu Irene H, Hemond Harold F
Department of Civil and Environmental Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139 USA.
IEEE Sens J. 2020 Feb;20(3):1509-1526. doi: 10.1109/jsen.2019.2946968. Epub 2019 Oct 11.
Eddy Correlation (EC) is a technique that can be used to measure transport of substances in aquatic ecosystems between bottom sediments and the overlying water (i.e. benthic fluxes). Based on high-speed, simultaneous, and co-located velocity and concentration measurements, EC has been successfully used in a variety of freshwater and marine settings to determine benthic fluxes of dissolved oxygen. Application to a larger range of compounds is limited, however, by the lack of suitable chemical sensors. Here, we describe FACT, a novel, high-speed, multi-function sensor created to expand the range of benthic fluxes that can be measured with EC. An optical fiber spectrofluorometer with a proximally located conductivity cell and thermistor, FACT enables benthic flux measurements of fluorescing compounds, such as fluorescent dissolved organic matter, as well as of heat and salinity which can be used as tracers for submarine groundwater discharge. The high bandwidth and open-beam geometry of the fluorescence sensor are particularly beneficial for EC measurements. FACT was integrated with a velocity sensor into a full EC system capable of simultaneous benthic flux measurements of fluorescing compounds, heat, and salinity. Tested in a laboratory tank, fluxes measured by all three sensors were found to track each other as well as compare favorably with expected values. Furthermore, the ability to measure fluxes of multiple substances both extends the applicability of EC to a wider range of natural sites, and can provide insight into issues of sensing volume and time responses as they affect the application of EC to natural waters.
涡度相关法(EC)是一种可用于测量水生生态系统中底质沉积物与上覆水体之间物质传输(即底栖通量)的技术。基于高速、同步且共定位的流速和浓度测量,EC已成功应用于各种淡水和海洋环境中,以确定溶解氧的底栖通量。然而,由于缺乏合适的化学传感器,其在更广泛化合物中的应用受到限制。在此,我们介绍FACT,一种新型的高速多功能传感器,旨在扩大可通过EC测量的底栖通量范围。FACT是一种带有近端电导率传感器和热敏电阻的光纤荧光光谱仪,它能够测量荧光化合物(如荧光溶解有机物)的底栖通量,以及可作为海底地下水排放示踪剂的热量和盐度。荧光传感器的高带宽和开放式光束几何结构对EC测量尤为有利。FACT与流速传感器集成到一个完整的EC系统中,能够同时测量荧光化合物、热量和盐度的底栖通量。在实验室水槽中进行测试时,发现所有三个传感器测量的通量相互跟踪,并且与预期值相比表现良好。此外,测量多种物质通量的能力不仅将EC的适用性扩展到更广泛的自然场所,还能深入了解传感体积和时间响应问题,因为它们会影响EC在天然水体中的应用。