Nagao Yuki
School of Materials Science, Japan Advanced Institute of Science and Technology, Nomi, Japan.
Sci Technol Adv Mater. 2020 Jan 30;21(1):79-91. doi: 10.1080/14686996.2020.1722740. eCollection 2020.
Several current topics are introduced in this review, with particular attention to highly proton-conductive polymer thin films with organized structure and molecularly oriented structure. Organized structure and molecularly oriented structure are anticipated as more promising approaches than conventional less-molecular-ordered structure to elucidate mechanisms of high proton conduction and control proton conduction. This review introduces related polymer materials and molecular design using lyotropic liquid crystals and hydrogen bond networks for high proton conduction. It also outlines the use of substrate surfaces and external fields, such as pressure and centrifugal force, for organizing structures and molecularly oriented structures.
本综述介绍了几个当前的主题，特别关注具有有序结构和分子取向结构的高质子传导聚合物薄膜。有序结构和分子取向结构被认为是比传统的低分子有序结构更有前景的方法，用于阐明高质子传导机制和控制质子传导。本综述介绍了相关的聚合物材料以及使用溶致液晶和氢键网络进行高质子传导的分子设计。它还概述了利用基底表面和外部场，如压力和离心力，来构建结构和分子取向结构。
