Department of Applied Chemistry, Waseda University, 3-4-1, Okubo, Shinjuku, Tokyo 169-8555, Japan.
Department of Energy Science and Technology, Myongji University, Nam-dong, Cheoin-gu, Yongin-si, Gyeonggi-do 449-728, South Korea.
Chem Commun (Camb). 2020 Mar 19;56(23):3365-3368. doi: 10.1039/d0cc00482k.
Low-temperature heterogeneous catalytic reaction in an electric field is anticipated as a novel approach for on-demand and small-scale catalytic processes. This report quantitatively reveals the important role of proton coverage on the catalyst support for catalytic ammonia synthesis in an electric field, which shows an anti-Arrhenius behaviour.
低温电场非均相催化反应有望成为按需、小规模催化过程的一种新方法。本报告定量揭示了质子覆盖催化剂载体在电场中催化氨合成反应中的重要作用，其表现出反阿累尼乌斯行为。
